Inkjet Image Recording on Non-Porous Substrates Without Color Bleeding

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Solution Overview

Problem

Existing image recording methods on non-permeable substrates face issues of bleeding between colors and dot embedding during multicolor image recording, which degrade the color gamut and image quality.

Innovation Solution

An image recording method involving a pretreatment liquid with water, an aggregating agent, and a resin, followed by specific inks with controlled parameters such as droplet volume, contact angle, acid value, solid content, and droplet spacing, is applied in a sequential order to suppress bleeding and dot embedding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a pretreatment liquid containing water, an aggregating agent, and a resin is applied followed by ink jet inks onto a non-permeable substrate, then multicolor image recording is enabled, but bleeding between colors and dot embedding occur

Engineering Contradiction:
Improvemulticolor image recording capabilityVSAvoidimage quality (bleeding and dot embedding)
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by precisely controlling the contact angle θ of the first ink within 20-60 degrees and the droplet volume V1 within 0.5-5 pL. These parameter optimizations prevent both bleeding between colors and dot embedding while maintaining multicolor image recording capability on non-permeable substrates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses preliminary action by applying a pretreatment liquid containing water, an aggregating agent, and a resin before ink jet application. This pretreatment layer is applied in advance to prepare the non-permeable substrate surface, enabling subsequent ink deposition without bleeding or dot embedding issues

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If conventional ink jet parameters are used on non-permeable substrates, then application simplicity is maintained, but color gamut decreases due to dot embedding

Engineering Contradiction:
Improveink application simplicityVSAvoidcolor gamut
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent changes the droplet volume parameter V1 to 0.5-5 pL and contact angle θ to 20-60 degrees, which prevents dot embedding and preserves color gamut while maintaining ease of operation through ink jet application on non-permeable substrates

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If ink droplet volume and contact angle are not controlled, then application process is simple, but bleeding between colors occurs

Engineering Contradiction:
Improveapplication process complexityVSAvoidcolor separation precision
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent controls the contact angle θ within 20-60 degrees and droplet volume V1 within 0.5-5 pL to prevent bleeding between colors. This parameter optimization achieves color separation precision without significantly increasing application process complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs feedback by measuring and controlling the contact angle θ of the first ink after pretreatment liquid application. This feedback mechanism ensures that the contact angle remains within the optimal 20-60 degree range, preventing bleeding while maintaining process simplicity

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively suppresses bleeding and dot embedding, enhancing the color gamut and image quality on non-permeable substrates by optimizing ink application parameters.

Implementation Method 1

a multicolor image can be recorded by applying a pretreatment liquid containing water, an aggregating agent, and a resin

Methodology Applied
Scientific EffectAggregation: Coagulation

Implementation Method 2

θ represents a contact angle of the first ink at a time point when T seconds have elapsed after the first ink has landed on the region onto which the pretreatment liquid has been applied

Methodology Applied
Scientific EffectContact angle: Surface Tension

Data Source

PatentEP4684976A1Image recording method
Publication Date: 2026.01.28 FUJIFILM CORP
  • EP4684976A1 patent drawingFigure 1~2
  • EP4684976A1 patent drawing
  • EP4684976A1 patent drawing

AI summary

An image recording method including a step of applying a pretreatment liquid, a first ink, and a second ink in this order onto a non-permeable substrate, in which a value (1) is 28.0 to 35.0 and a value (2) is -200 to 200. V1 represents a volume (pL) of a liquid droplet of the first ink, θ represents a contact angle (°) of the first ink, Av1 represents an acid value (mgKOH/g) of the first ink, Av2 represents an acid value (mgKOH/g) of the second ink, S1 represents a solid content amount (% by mass) of the first ink, S2 represents a solid content amount (% by mass) of the second ink, and T represents a droplet interval (seconds) between the first ink and the second ink. Value1=V11/3×1+cosθ×14 Value2=Av1/S1−Av2/S2×Av2−Av1/T