Inkjet Recording Ink Set Surface Tension Control

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Solution Overview

Problem

Current inkjet recording inks face challenges with water resistance, weather resistance, and color bleed, especially on poorly water-absorbable coated papers, which affect image quality and paper integrity.

Innovation Solution

A recording ink set comprising black, cyan, and magenta inks with water-insoluble color materials, water-soluble organic solvents, and surfactants, where the surface tension of solvents in non-black inks is higher than in black ink, and the ink set has controlled viscosity and contact angles to prevent color bleed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If pigment inks are used to improve water resistance and weather resistance, then image durability is improved, but color bleed on regular paper increases

Engineering Contradiction:
Improvewater resistanceVSAvoidcolor bleed
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by carefully controlling the surface tension of the ink within 20-40 mN/m and viscosity within 6-20 mPa·s at 25°C. These parameter optimizations allow the pigment ink to achieve both water resistance and reduced color bleed on regular paper by balancing the ink's interaction with the paper fibers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses different surfactant combinations and ratios tailored to specific paper types. The ink formulation adjusts its local properties (surface tension, wetting characteristics) to match the absorption characteristics of either regular paper or coated paper, thereby preventing color bleed while maintaining water resistance.

Inventive Principle:
Principle #3Local quality

2Reliability

If water-insoluble color materials are used to improve water resistance, then image water resistance is improved, but color bleed on poorly water-absorbable coated paper increases

Engineering Contradiction:
Improveimage water resistanceVSAvoidcolor bleed on coated paper
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes surface tension parameters to 20-40 mN/m and viscosity to 6-20 mPa·s, which enables the ink to properly penetrate and bond with poorly water-absorbable coated papers. This parameter control prevents the ink from pooling on the surface and causing color bleed while maintaining water resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs surfactants as intermediary substances that facilitate proper ink-paper interaction on coated surfaces. The surfactant system acts as a mediator between the water-insoluble pigment and the hydrophobic coated paper surface, enabling controlled absorption and preventing color bleed.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If large difference in physical properties between inks is used to control color bleed, then color bleed is reduced, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvecolor bleedVSAvoidink nozzle selection complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent maintains homogeneity across all ink colors by keeping viscosity differences within 0.7-4.0 mPa·s and surface tension within 20-40 mN/m. This homogeneous formulation approach eliminates the need for complex nozzle selection and device design while still preventing color bleed through optimized physical properties.

Inventive Principle:
Principle #33Homogeneity

Solution Approach 2:

The patent creates a universal ink formulation that works across all color channels (black, cyan, magenta, yellow) with consistent physical properties. This multi-functional ink design prevents color bleed without requiring different nozzle configurations or complex printing system adjustments.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Ease of operation

If high water content ink is used to improve ease of operation, then ink flow is improved, but paper cockling increases

Engineering Contradiction:
Improveink discharge stabilityVSAvoidpaper cockling
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes the water content parameter to balance ink flow properties with paper integrity. By controlling water content alongside surface tension (20-40 mN/m) and viscosity (6-20 mPa·s), the ink maintains stable discharge and good flow characteristics while minimizing excessive water absorption that causes paper cockling.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves excellent image formation with improved water and weather resistance, reducing color bleed on regular and poorly water-absorbable papers, ensuring high-quality prints without paper deformation.

Implementation Method 1

the surface tension of the water-soluble organic solvent(s) used only for the inks other than the black ink is higher than that of the water-soluble organic solvent used only for the black ink

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

the initial wet property of ink relative to recording media affects color bleed

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

a surfactant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 4

the difference in dynamic contact angle, and the rate of dot-dimension change

Methodology Applied
Scientific EffectContact angle: Wetting

Data Source

PatentEP1940979B1Recording ink, recording ink set, records, ink cartridge, recording method, and inkjet recording apparatus
Publication Date: 2016.06.08 RICOH CO LTD
  • EP1940979B1 patent drawingFigure 1~2
  • EP1940979B1 patent drawingFigure 3
  • EP1940979B1 patent drawingFigure 4

AI summary

The present invention provides a recording ink set containing a black ink, a cyan ink, a magenta ink, and a yellow ink, each of which contains water, a water-insoluble color material, a water-soluble organic solvent, and a surfactant, wherein the black ink and at least one of the inks other than the black ink respectively contain a different water-soluble organic solvent; and the surface tension of the water-soluble organic solvent(s) used only for the inks other than the black ink is higher than that of the water-soluble organic solvent used only for the black ink; and the present invention also provides a recording method using the recording ink set.