Inkjet-Printed SAM Layers for Spatial Surface Energy Control

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Solution Overview

Problem

Existing methods for configuring surface energies and hydrophilicities of substrates are complex, expensive, and time-consuming, often failing to achieve spatial control effectively.

Innovation Solution

Inkjet printing of self-assembled monolayer (SAM) structures using a SAM composition with an active component and hydrophobic tail, allowing localized printing and reaction on substrate surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional methods are used to configure surface energies and hydrophilicities, then surface modification can be achieved, but the process becomes complex, expensive, and time-consuming without spatial control

Engineering Contradiction:
Improveease of surface modificationVSAvoidprocess complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The substrate surface is divided into multiple regions, with different areas receiving different SAM compositions or treatment conditions. This segmentation enables spatial control of surface properties while using a simplified inkjet printing process rather than complex multi-step surface modification methods.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Traditional mechanical or chemical surface modification methods are replaced with inkjet printing of SAM compositions. This substitution uses a well-established, simple printing technology to achieve surface modification, eliminating the need for complex equipment and procedures while maintaining ease of manufacture.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Ease of manufacture

If traditional methods are used to configure surface energies and hydrophilicities, then surface modification can be achieved, but the process becomes expensive and time-consuming

Engineering Contradiction:
Improveease of surface modificationVSAvoidprocessing time and cost
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The SAM composition is prepared in advance with the desired active components and hydrophobic tails, and the inkjet printing system is pre-configured. This preliminary preparation allows for rapid, cost-effective surface modification without time-consuming on-site processing steps, improving productivity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Complex and expensive traditional surface modification equipment is replaced with affordable inkjet printing technology. This substitution maintains ease of manufacture while significantly reducing processing time and cost, thereby improving productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If traditional methods are used to configure surface energies and hydrophilicities, then surface modification can be achieved, but spatial control is lost

Engineering Contradiction:
Improveease of surface modificationVSAvoidspatial control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The substrate is divided into distinct printing regions, with each region receiving targeted SAM composition deposition through inkjet printing. This segmentation provides precise spatial control over surface energy and hydrophilicity distribution, allowing different areas to have customized properties while maintaining ease of manufacture.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the substrate are given different local qualities by selectively printing specific SAM compositions in different areas. This local quality approach enables precise spatial control of surface properties while using a simple, easy-to-implement inkjet printing process.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Facilitates simple, cost-effective, and time-efficient spatial control of surface energies and hydrophilicities, enabling precise formation of optical films and devices with improved quality and functionality.

Implementation Method 1

printing one or more SAM layers on a substrate surface of the substrate in a localized manner such that a portion of the substrate surface is left exposed to a processing region of the inkjet chamber. The printing includes spraying one or more subsections of the substrate surface with an ink

Methodology Applied
Scientific EffectInkjet printing:

Implementation Method 2

forming self-assembled monolayer (SAM) structures

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 3

allowing the one or more SAM layers to react with the substrate surface

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

The SAM composition includes an active component, and a hydrophobic tail

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS12384185B2Methods, systems, and apparatus for inkjet printing self-assembled monoloayer (SAM) structures on substrates
Publication Date: 2025.08.12 APPLIED MATERIALS INC
  • US12384185B2 patent drawing
  • US12384185B2 patent drawing
  • US12384185B2 patent drawing

AI summary

Embodiments of the present disclosure relate to methods, systems, and apparatus for inkjet printing self-assembled monolayer (SAM) structures on substrates. In one embodiment, which can be combined with other embodiments, one or more SAM layers are printed on a substrate surface of a substrate in a localized manner such that a portion of the substrate surface is left exposed to a processing region of the inkjet chamber. The printing includes spraying one or more subsections of the substrate surface with an ink, the ink having a SAM composition. The SAM composition includes an active component, and a hydrophobic tail.