Inline Silicon Deposition in Pickling Circuits for Clog Prevention

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Solution Overview

Problem

Pickling plants with high silicon content steel strips face frequent clogging and maintenance issues due to the formation of insoluble silicon compounds, which existing methods struggle to address efficiently, leading to reduced availability and increased energy consumption.

Innovation Solution

A device with a flocculation and deposition system integrated into the pickling circuit, utilizing a circulation pump and heating device to maintain process temperature, and a lamella separating device for efficient deposition of undissolved silicon compounds directly from the main volume flow, eliminating the need for separate cooling and reheating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional pickling methods are used for high silicon content steel strips, then pickling process can be performed, but insoluble silicon compounds accumulate and cause frequent clogging and maintenance issues

Engineering Contradiction:
Improvepickling process continuityVSAvoidplant availability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements continuous inline deposition of silicon compounds directly in the pickling circuit, eliminating interruptions for maintenance. The circulation pump continuously circulates pickling fluid through the deposition device, ensuring uninterrupted pickling operation while continuously removing silicon compounds.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent extracts undissolved silicon compounds from the pickling fluid using a deposition device with a lamella separating element. This extraction happens continuously within the pickling circuit, removing the harmful accumulations before they can cause clogging and maintain plant availability.

Inventive Principle:
Principle #2Taking out (Extraction)

2Reliability

If existing deposition methods are used, then silicon compounds can be removed, but separate cooling and reheating are required increasing energy consumption

Engineering Contradiction:
Improvesilicon compound deposition efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent merges the deposition process with the existing pickling circuit circulation system. The circulation pump that already exists for pickling operations is used to drive the deposition process, eliminating the need for separate cooling and reheating systems. The heating device integrated into the pressure line maintains process temperature without additional energy-intensive cooling and reheating cycles.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The circulation pump serves dual functions: it circulates pickling fluid for the pickling process and simultaneously drives the deposition of silicon compounds. The heating device also serves dual purposes by maintaining pickling fluid temperature and preventing cooling during the deposition process, thereby reducing overall energy consumption.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If microfiltration is used to remove silicon compounds, then separation can be achieved, but membranes have short service lives due to process conditions

Engineering Contradiction:
Improveseparation effectivenessVSAvoidmembrane service life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent replaces the mechanical membrane filtration system with a gravitational deposition system using a lamella separating element. This substitution eliminates the membrane component that suffers from short service life in harsh pickling conditions, while maintaining effective separation of silicon compounds through gravity-driven settling in the lamella channels.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of operation

If washing back with lye is used to remove residues, then cleaning can be achieved, but additional substances and expensive apparatuses are required

Engineering Contradiction:
Improveresidue removal capabilityVSAvoidapparatus requirements
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent enables the pickling fluid to clean itself by continuously circulating through the deposition device where silicon compounds are automatically deposited and removed. This self-cleaning mechanism eliminates the need for external washing back operations with lye, reducing both chemical consumption and apparatus requirements.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables continuous inline operation with improved pickling fluid quality, reduced maintenance intervals, and lower energy consumption by effectively depositing undissolved silicon compounds from the entire main volume flow, enhancing the pickling plant's availability and operational efficiency.

Implementation Method 1

a circulation pump having a maximum pump capacity of from 500 to 600 cubic meters per hour for circulating a main volume flow of pickling fluid from the pickling tank through the return line into the circuit tank and via the pressure line back into the pickling tank

Methodology Applied
Scientific EffectPump: Pump

Implementation Method 2

a heating device arranged in the pressure line for heating the main volume flow passed through the pressure line to a process temperature Tp prevailing in the pickling tank

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

at least one flocculation aid is introduced into the main volume flow by means of a flocculation device having one or more mixing zone containers

Methodology Applied
Scientific EffectFlocculation: Flocculation

Implementation Method 4

undissolved silicon compounds are deposited directly from the main volume flow by means of a deposition device arranged in the circuit tank

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Data Source

PatentUS20240200202A1Inline silicon deposition in a pickling plant
Publication Date: 2024.06.20 PRIMETALS TECH AUSTRIA GMBH
  • US20240200202A1 patent drawing
  • US20240200202A1 patent drawing

AI summary

A device and a method for depositing undissolved materials, in particular undissolved silicon compounds, from a pickling fluid in a pickling plant. A pickling circuit of the pickling plant has a pickling tank for pickling metal strips, a return line between the pickling tank and a circuit tank, a circulation pump for circulating a main volume flow of pickling fluid from the pickling tank, and a heating device arranged in a pressure line between the circuit tank and the pickling tank. The device includes a flocculation device for introducing at least one flocculant into the main volume flow, and a deposition device in the circuit tank and preferably designed as an inclined clarifying device, for the sedimentation of undissolved materials directly from the main volume flow. When pickling silicon-containing steel strips (electrical steel strips), an at least two-stage flocculation can be carried out using two or more mixing zone containers.