Inorganic Binder Phosphor Wheel Thermal Stability

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Solution Overview

Problem

Phosphor wheels in high-power laser projection systems face short operational life and reduced light conversion efficiency due to thermal instability of silicone binders, while ceramic binders offer high temperature stability but are costly and require high sintering temperatures.

Innovation Solution

The use of an inorganic binder, such as sodium silicate, which provides thermal stability up to 200°C and beyond, with a weight ratio of SiO2:Na2O from 2:1 to 3.75:1, and a bonding strength suitable for high-temperature applications, applied to a substrate in a phosphor wheel for wavelength conversion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If silicone binder is used in phosphor wheel, then bonding strength and transparency are improved, but thermal stability deteriorates at temperatures over 200°C

Engineering Contradiction:
Improvebonding strengthVSAvoidthermal stability
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the binder by incorporating inorganic materials (such as glass ceramics, metal oxides, or ceramic particles) into the silicone binder formulation. This modification allows the binder to maintain its adhesive properties while gaining thermal stability up to 300°C or higher, resolving the contradiction between bonding strength and thermal stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite binder material by combining organic silicone components with inorganic fillers (glass ceramics, metal oxides, ceramic particles). This composite structure leverages the adhesive properties of silicone while the inorganic components provide high-temperature stability, effectively resolving the contradiction between bonding strength and thermal resistance.

Inventive Principle:
Principle #40Composite materials

2Temperature

If ceramic binder is used in phosphor wheel, then thermal stability is improved, but manufacturing cost and sintering temperature increase

Engineering Contradiction:
Improvethermal stabilityVSAvoidmanufacturing cost
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent uses a modified silicone binder containing inorganic components as an intermediary material that bridges the gap between purely organic binders and fully ceramic binders. This intermediate solution provides ceramic-like thermal stability while maintaining the ease of application and lower processing temperatures characteristic of organic binders, thereby reducing manufacturing costs and avoiding high sintering requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent adjusts the formulation parameters of the binder by incorporating specific ratios of inorganic fillers (glass ceramics, metal oxides, ceramic particles) into the silicone matrix. This parameter optimization achieves thermal stability comparable to ceramic binders while maintaining lower processing temperatures and reduced manufacturing complexity, thus resolving the cost and manufacturability contradiction.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If phosphor-in-silicone product is used, then light conversion efficiency is improved, but operational life decreases at high temperatures

Engineering Contradiction:
Improvelight conversion efficiencyVSAvoidoperational life
Core Design Contradiction:
Use of energy by moving objectVSDuration of action of stationary object

Solution Approach 1:

The patent creates a composite binder system combining silicone with inorganic materials (glass ceramics, metal oxides, ceramic particles) that maintains the optical clarity and light conversion efficiency of pure silicone while adding thermal stability. This composite structure prevents degradation at high temperatures, thereby extending operational life without sacrificing light conversion performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the thermal and chemical parameters of the binder by incorporating heat-resistant inorganic components. This parameter change allows the phosphor-in-binder product to maintain its light conversion efficiency at elevated temperatures while resisting degradation, thus extending operational life from limited hours to potentially unlimited service life in high-temperature applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The inorganic binder maintains high light transmittance and bonding strength, extending the operational life and efficiency of phosphor wheels in high-power systems without significant cost increases, offering a durable and efficient solution for high-temperature light conversion.

Implementation Method 1

Wavelength conversion materials (phosphors) on the optically-active radial portion generate emission light of a different wavelength from incident excitation light

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 2

The inorganic binder maintains high light transmittance and bonding strength

Methodology Applied
Scientific EffectLight transmission: Light

Data Source

PatentEP4235298B1Phosphor wheel with inorganic binder
Publication Date: 2024.11.13 MATERION PRECISION OPTICS SHANGHAI LTD
  • EP4235298B1 patent drawingFigure 1A~1B
  • EP4235298B1 patent drawingFigure 2A~2B
  • EP4235298B1 patent drawing

AI summary

A light conversion device is disclosed. The light conversion device includes a substrate and a wavelength conversion element. The wavelength conversion element includes an inorganic binder, such as sodium silicate. Also disclosed are phosphor wheels and light engines including such phosphor wheels. Further disclosed are high-power laser projection display systems comprising a laser having a power of from about 60W and about 300W and a light conversion device. The use of an inorganic binder permits high thermal stability at reasonable cost.