Inorganic-Electrode Ion Sensor for Consistent Multi-Sensor Measurement

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Solution Overview

Problem

Conventional ion sensors exhibit variations in measurement results when multiple sensors are used, making it difficult to distinguish whether the variation is due to ion concentration or sensor variability.

Innovation Solution

A current measurement type ion sensor with a specific structure comprising a first electrode, an organic phase retaining layer, and a second electrode, where the electrodes are connected to a voltage application and current measuring unit, allowing for consistent measurement by moving target ions between the electrodes and measuring the resulting current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional ion sensor with a conductive polymer film is used, then the electrode potential can be fixed in the organic phase, but the measurement results vary among multiple ion sensors

Engineering Contradiction:
Improvemeasurement consistencyVSAvoidmeasurement result accuracy
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent changes the material parameter of the electrode from conductive polymer to inorganic compound (such as metal oxide or semiconductor), which fundamentally alters the electrode's electrical properties and ion interaction characteristics, leading to more consistent measurement results across multiple sensors

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite structures where the inorganic compound electrode is combined with the organic phase retaining layer containing ionophores, creating a hybrid system that leverages the stability of inorganic materials and the ion-selective properties of organic compounds to achieve both reliability and precision

Inventive Principle:
Principle #40Composite materials

2Productivity

If multiple ion sensors are used for measurement, then more samples can be measured, but it becomes difficult to distinguish whether variation is due to ion concentration or sensor variability

Engineering Contradiction:
Improvemeasurement throughputVSAvoiddata interpretation accuracy
Core Design Contradiction:
ProductivityVSLoss of information

Solution Approach 1:

By changing the electrode material to inorganic compounds with more stable and predictable electrical characteristics, the patent reduces sensor-to-sensor variability, allowing multiple sensors to be used simultaneously without compromising data interpretation accuracy

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ion sensor provides consistent measurement results across multiple sensors by minimizing variations, enabling accurate and reliable ion detection without the need for calibration.

Implementation Method 1

an organic phase retaining layer containing an organic phase capable of forming an interface with a sample containing a target ion

Methodology Applied
Scientific EffectInterface formation:

Implementation Method 2

moving the target ion contained in the sample to the organic phase by applying a voltage between the first electrode and the second electrode

Methodology Applied
Scientific EffectElectrophoresis: Electrophoresis

Implementation Method 3

measuring a current flowing between the first electrode and the second electrode

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS12429451B2Ion sensor and method for measuring ions
Publication Date: 2025.09.30 SYSMEX CORP
  • US12429451B2 patent drawing
  • US12429451B2 patent drawing
  • US12429451B2 patent drawing

AI summary

The ion sensor of the present invention is a current measurement type ion sensor that measures a current to measure a target ion, and includes an organic phase retaining layer containing an organic phase capable of forming an interface with the sample containing the target ion, a first electrode to which the organic phase retaining layer is laminated and containing a first insertion material composed of an inorganic compound, a second electrode arranged so as to face the organic phase holding layer and in contact with the sample.