InSb Photodiodes with AlInSb Passivation for Noise Reduction

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Solution Overview

Problem

Conventional manufacturing processes for InSb-based infrared photodiodes and sensor arrays introduce surface defects, leading to high surface recombination velocity, increased dark current, and noise equivalent power, necessitating cryogenic cooling to partially recover sensitivity, which is costly and maintenance-intensive.

Innovation Solution

Forming a passivation layer from a wide bandgap material like AlInSb on the InSb substrate before creating photodiode detector regions, allowing P+ species implantation through this layer to form P+ regions, thereby reducing substrate defects and improving noise performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional manufacturing processes are used to create photodiode detector regions, then detector functionality is achieved, but surface defects are introduced leading to high surface recombination velocity and increased dark current

Engineering Contradiction:
Improvedetector functionalityVSAvoidsurface defects, surface recombination velocity, dark current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A passivation layer is formed on the InSb substrate surface before creating the photodiode detector regions. This preliminary passivation action protects the substrate from damage during subsequent manufacturing processes, preventing surface defects from forming in the first place rather than attempting to repair them later.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The passivation layer acts as an intermediary protective barrier between the manufacturing processes and the InSb substrate. This intermediate layer prevents direct contact between harsh manufacturing conditions and the sensitive substrate surface, thereby reducing surface recombination velocity and dark current while allowing detector functionality to be achieved.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If cryogenic cooling is applied to recover sensitivity, then noise performance improves, but operational cost and maintenance complexity increase

Engineering Contradiction:
Improvenoise performance, sensitivityVSAvoidcooling system complexity, maintenance requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention converts the harmful effect of surface defects into a benefit by applying passivation. The passivation layer transforms the problematic substrate surface into a protected, low-recombination surface, thereby improving noise performance and sensitivity without requiring cryogenic cooling systems.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Instead of implementing expensive, complex, and maintenance-intensive cryogenic cooling systems, the invention uses a simple, inexpensive passivation layer that provides the necessary noise performance improvement. The passivation layer is a cost-effective alternative that eliminates the need for costly cooling infrastructure.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-generated harmful factors

If passivation layer is formed before detector region creation, then surface defects are reduced, but additional manufacturing steps are required

Engineering Contradiction:
Improvesurface defects, dark currentVSAvoidmanufacturing process steps
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The passivation layer formation is merged with the detector region creation process. The passivation layer is formed first, then detector regions are created through implantation or epitaxial growth that integrates with the existing passivation structure, combining protection and functionality in a unified manufacturing approach.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in fewer substrate defects, enhancing the noise performance of sensor arrays and reducing the need for cryogenic cooling, thereby improving sensitivity and operational efficiency.

Implementation Method 1

high surface recombination velocity

Methodology Applied
Scientific EffectSurface recombination:

Implementation Method 2

selectively implanting P+ species through the passivation layer to form P+ regions

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 3

InSb-based photodiode detectors are used in many infrared sensor applications

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS7544532B2Infrared photodiodes and sensor arrays with improved passivation layers and methods of manufacture
Publication Date: 2009.06.09 RAYTHEON CO
  • US7544532B2 patent drawing
  • US7544532B2 patent drawing
  • US7544532B2 patent drawing

AI summary

InSb infrared photodiodes and sensor arrays with improved passivation layers and methods for making same are disclosed. In the method, a passivation layer of AlInSb is deposited on an n-type InSb substrate using molecular beam epitaxy before photodiode detector regions are formed in the n-type substrate. Then, a suitable P+ dopant is implanted directly through the AlInSb passivation layer to form photodiode detector regions. Next, the AlInSb passivation layer is selectively removed, exposing first regions of the InSb substrate, and gate contacts are formed in the first regions of the InSb substrate. Then, additional portions of the AlInSb passivation layer are selectively removed above the photodiode detectors exposing second regions. Next, metal contacts are formed in the second regions, and bump contacts are formed atop the metal contacts. Then, an antireflection coating is applied to a side of the substrate opposite from the side having the metal and bump contacts. Forming the AlInSb passivation layer before the photodiode detector regions reduces the number of defects created in the n-type InSb substrate during fabrication in comparison to conventional methods and improves the noise performance of InSb photodiodes and sensor arrays incorporating the improved passivation layer.