Insulated Pipe Foaming via Catalyst Timing

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Solution Overview

Problem

Existing methods for producing insulated pipes face challenges such as high thermal conductivity due to large cell diameters, uneven foam density distribution, and limited insulation layer thickness, which increase production time and costs, while also being sensitive to environmental conditions during on-site assembly.

Innovation Solution

A method involving a polyurethane system with a catalyst that initiates polymerization before filling is complete, using a polyol mixture with high viscosity and specific amine catalysts to achieve rapid foaming and uniform density, allowing for shorter start times and increased insulation layer thickness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If polyurethane system with long start time is used, then good pre-distribution in the pipe is achieved, but cell diameters increase leading to higher thermal conductivity

Engineering Contradiction:
Improvefoam distribution uniformityVSAvoidthermal conductivity
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The patent changes the chemical parameters of the polyurethane system by selecting specific polyols with controlled reactivity and using particular catalysts (organometallic compounds like tin octoate) to adjust the start time to be equal to or slightly less than filling time. This parameter optimization allows the foam to begin forming at the optimal moment, creating small cell diameters (0.3-1.5mm) while maintaining uniform distribution throughout the pipe.

Inventive Principle:
Principle #35Parameter changes

2Volume of stationary object

If slow reaction profile is used, then larger pipe dimensions can be filled, but production time increases

Engineering Contradiction:
Improvepipe insulation thicknessVSAvoidproduction time
Core Design Contradiction:
Volume of stationary objectVSLoss of time

Solution Approach 1:

The patent applies preliminary action by ensuring the polyurethane system starts reacting exactly when filling completes or slightly before. This timing control allows the foaming process to begin with optimal conditions already in place, enabling rapid cell formation and hardening that completes in 5-15 minutes, significantly reducing production time while accommodating large pipe dimensions up to 2 meters in diameter.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If polyol component with low viscosity is used, then good flowability is achieved, but filling time increases

Engineering Contradiction:
ImproveflowabilityVSAvoidfilling time
Core Design Contradiction:
Ease of operationVSLoss of time

Solution Approach 1:

The patent optimizes the viscosity parameter of the polyol component to a specific range (500-2000 mPas at 20°C) that balances flowability and filling speed. This parameter selection, combined with the controlled start time approach, allows the low-viscosity polyol to flow rapidly into the pipe during filling while the reaction begins at the optimal moment, eliminating the need for excessively long filling times associated with very low viscosity materials.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in insulated pipes with low thermal conductivity, improved density distribution, and increased productivity, enabling longer pipe segments with enhanced insulation efficiency and reduced production costs.

Implementation Method 1

a polyurethane system comprising at least one isocyanate component (a), at least one polyol mixture (b) and at least one catalyst... foaming and allowing the polyurethane system to harden

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

Pipes insulated with polyurethane foams... due to its excellent insulating properties

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentEP2751157B1Method for producing insulated pipes having improved properties
Publication Date: 2019.10.09 BASF SE

AI summary

The invention relates to a method for producing insulated pipes, to the use of a polyurethane system comprising an isocyanate component (a), a polyol mixture (b), and at least one catalyst to produce insulated pipes, wherein the starting time for the polyurethane system is less than the time for filling the pipe with the polyurethane system, to the use of special amines as catalysts in a polyurethane system for producing insulated pipes, and to an insulated pipe that can be obtained by the method according to the invention.