Insulating Polymer Adhesion for Bioelectrode Interfaces

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Solution Overview

Problem

Conventional methods for producing composite materials adhere hydrogel to electrodes using conductive polymers, limiting adhesion to the surface and requiring conductive polymer layers, which can cause issues like leak current during electrostimulation and noise in bioelectrical signal measurements.

Innovation Solution

A composite material is developed where insulating polymers with low conductivity, such as polyacrylamide and PPEGDA, extend from the substrate surface into a hydrogel porous body, providing firm adhesion through radical polymerization reactions, allowing for the use of both insulating and conductive substrates without relying on electron conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conductive polymers are used to adhere hydrogel to electrode, then adhesion is achieved, but leak current and noise occur during electrostimulation and bioelectrical signal measurements

Engineering Contradiction:
Improveadhesion strengthVSAvoidleak current and noise
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent divides the adhesive layer into two distinct segments: an insulating polymer layer in direct contact with the hydrogel for adhesion, and a conductive polymer layer on the outer surface for electrical functionality. This segmentation allows each layer to perform its specific function without interfering with the other, eliminating leak current and noise while maintaining strong adhesion.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The insulating polymer acts as an intermediary layer between the hydrogel and the conductive polymer/external environment. This intermediary prevents direct electrical contact between the conductive polymer and the hydrogel/body, thereby blocking leak current and noise transmission while still allowing mechanical adhesion to occur.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If only conductive polymer layer is provided on surface layer of gel, then adhesion is simplified, but adhesion of insulating polymer to porous body is required for broader application

Engineering Contradiction:
Improveadhesion process simplicityVSAvoidapplication scope
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The insulating polymer layer serves multiple functions: it provides adhesion to the hydrogel, acts as an electrical insulator to prevent leak current and noise, and creates a suitable substrate for the conductive polymer layer. This multi-functionality makes the composite material structure universally applicable to various electrostimulation and bioelectrical signal measurement applications.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables firm adhesion of substrates to porous bodies, enhancing the stability and biocompatibility of bioelectrical interfaces, reducing noise and leak currents, and allowing for flexible substrate arrangements suitable for bioelectrical signal measurements and electrostimulation.

Implementation Method 1

performing polymerization to carry out a polymerization reaction of the monomers with the polymerization initiators being a polymerization starting point. The polymerization reaction of the monomers in the presently disclosed method of producing composite material is preferably a radical polymerization reaction.

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Data Source

PatentUS10525681B2Composite material and method of producing composite material
Publication Date: 2020.01.07 TOHOKU UNIV
  • US10525681B2 patent drawing
  • US10525681B2 patent drawing
  • US10525681B2 patent drawing

AI summary

A composite material including a substrate, a porous body provided on the substrate, and insulating polymers starting from a surface of the substrate and extending inside the porous body, and a method of producing the composite material.