In-Sn-Zn-O Semiconductor Etching for Transistor Miniaturization

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Solution Overview

Problem

In—Sn—Zn—O-based oxide semiconductor layers are difficult to etch using wet etching methods, which limits miniaturization and controllability in semiconductor device manufacturing, as wet etching is isotropic and lacks precision.

Innovation Solution

The use of dry etching techniques with gases containing chlorine, such as Cl2, BCl3, or SiCl4, along with rare gases, oxygen, or fluorine, to selectively etch In—Sn—Zn—O-based semiconductor layers, allowing for the formation of island-shaped structures with controlled taper angles and minimal material removal, enabling miniaturization and improved controllability in transistor manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If wet etching is used to etch oxide semiconductor layers, then the etching process is simple and isotropic, but the manufacturing precision and controllability deteriorate, preventing miniaturization

Engineering Contradiction:
Improveetching process simplicityVSAvoidetching precision and controllability
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent replaces wet etching (chemical/liquid-based) with dry etching (gas-phase plasma-based) to achieve superior etching precision and controllability. The dry etching process using chlorine-containing gases provides anisotropic etching that enables precise pattern formation for miniaturized devices, while maintaining ease of manufacture through established semiconductor fabrication techniques

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the etching parameters by using specific chlorine-containing gases (Cl2, BCl3, SiCl4) in dry etching conditions, adjusting gas composition, flow rates, and plasma parameters to achieve optimal etching precision and controllability for oxide semiconductor layers while maintaining process simplicity

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If wet etching is used, then the process is easier to implement, but miniaturization of elements cannot be achieved due to isotropic etching characteristics

Engineering Contradiction:
Improveetching operation easeVSAvoidelement size for miniaturization
Core Design Contradiction:
Ease of operationVSLength of moving object

Solution Approach 1:

The patent substitutes wet etching with dry etching using chlorine-containing gases, which provides anisotropic etching characteristics essential for miniaturization. This replacement maintains operational ease through automated plasma control while enabling precise dimensional control for sub-micron element sizes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If wet etching with chemical solutions is used, then the process is simpler, but controllability deteriorates

Engineering Contradiction:
Improveetching process simplicityVSAvoidetching controllability
Core Design Contradiction:
Ease of manufactureVSEase of operation

Solution Approach 1:

The patent changes from liquid chemical solutions to gas-phase plasma with chlorine-containing gases, enabling precise control of etching parameters such as gas flow rate, pressure, temperature, and plasma power. This provides superior controllability while maintaining ease of manufacture through automated process control systems

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If dry etching with chlorine-containing gases is used, then manufacturing precision and controllability improve, but the device complexity increases

Engineering Contradiction:
Improveetching precisionVSAvoidetching process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent uses chlorine-containing gases (Cl2, BCl3, SiCl4) in dry etching to achieve high manufacturing precision through controlled plasma reactions. The process complexity is managed by optimizing gas composition, flow rates, and plasma parameters within established semiconductor fabrication frameworks

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the production of miniaturized transistors with improved field-effect mobility and reduced off-state current, achieving on-state current requirements for integrated circuits while maintaining high reliability and precision in semiconductor device fabrication.

Implementation Method 1

selectively removing the oxide semiconductor layer by dry etching with the use of a gas containing chlorine

Methodology Applied
Scientific EffectDry etching: Plasma

Implementation Method 2

An In—Sn—Zn—O-based oxide semiconductor layer can be etched by wet etching, whereas an oxide semiconductor layer containing SnO2, In2O3, or ZnO is difficult to etch by wet etching

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS9373708B2Method for manufacturing semiconductor device
Publication Date: 2016.06.21 SEMICON ENERGY LAB CO LTD
  • US9373708B2 patent drawing
  • US9373708B2 patent drawing
  • US9373708B2 patent drawing

AI summary

To establish a processing technique in manufacture of a semiconductor device including an In—Sn—Zn—O-based semiconductor. An In—Sn—Zn—O-based semiconductor layer is selectively etched by dry etching with the use of a gas containing chlorine such as Cl2, BCl3, SiCl4, or the like. In formation of a source electrode layer and a drain electrode layer, a conductive layer on and in contact with the In—Sn—Zn—O-based semiconductor layer can be selectively etched with little removal of the In—Sn—Zn—O-based semiconductor layer with the use of a gas containing oxygen or fluorine in addition to a gas containing chlorine.