Integrated Adsorber Head and Valve Design for Reverse-Flow Reactors

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Solution Overview

Problem

Conventional reverse-flow reactors (RFRs) face inefficiencies due to large void volumes, long cycle times, and high capital costs, primarily because of low heat transfer rates and inadequate valve durability, which limits their application in energy and petrochemical fields.

Innovation Solution

The design integrates poppet valves within the adsorber heads to minimize dead volume and enhance valve durability, allowing for rapid stream-switching and efficient gas management, thereby reducing cycle times and capital costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If conventional packing materials (checker brick, pebble beds) are used in reverse-flow reactors, then pressure drop is reduced, but volumetric heat transfer rate decreases

Engineering Contradiction:
Improvepressure dropVSAvoidvolumetric heat transfer rate
Core Design Contradiction:
Stress or pressureVSProductivity

Solution Approach 1:

The patent employs engineered packing materials with controlled porosity and surface area characteristics. These porous structures provide high geometric surface area (a_v) while maintaining acceptable pressure drop characteristics, enabling both efficient heat transfer and reasonable flow resistance in the reverse-flow reactor.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention uses composite packing structures that combine different materials and geometries to achieve optimal balance between heat transfer efficiency and pressure drop. The engineered packing integrates multiple functional properties in a single structured material system.

Inventive Principle:
Principle #40Composite materials

2Productivity

If engineered packing with high geometric surface area is used, then volumetric heat transfer rate increases, but pressure drop increases

Engineering Contradiction:
Improvevolumetric heat transfer rateVSAvoidpressure drop
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent optimizes key parameters of the engineered packing including pore size distribution, surface area-to-volume ratio, and material thermal conductivity. By carefully adjusting these parameters, the system achieves high volumetric heat transfer rates while controlling pressure drop within acceptable limits.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional valve systems are used in reverse-flow reactors, then gas volume management is simplified, but cycle time increases and valve durability decreases

Engineering Contradiction:
Improvegas volume managementVSAvoidcycle time
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent integrates the valve system directly with the reactor head structure, combining functions that were previously separate. This integration minimizes dead volume, reduces the number of components, and enables faster valve operation while improving durability through optimized structural design.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention employs dynamic valve mechanisms capable of rapid opening and closing operations. The valve design allows for quick response times, enabling shorter cycle times while maintaining effective gas volume management through coordinated valve actuation sequences.

Inventive Principle:
Principle #15Dynamics

4Productivity

If larger reactor volumes are used to compensate for low heat transfer rates, then desired chemical production is maintained, but capital costs increase

Engineering Contradiction:
Improvechemical productionVSAvoidreactor volume
Core Design Contradiction:
ProductivityVSVolume of stationary object

Solution Approach 1:

By using engineered porous packing materials with high surface area-to-volume ratios, the patent achieves high volumetric heat transfer rates that allow compact reactor designs. This eliminates the need for oversized reactors while maintaining desired chemical production levels, thereby reducing capital costs.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration minimizes unnecessary gas volumes, improves valve longevity, and increases operational efficiency, making reverse-flow adsorbers more suitable for high-temperature, high-productivity applications.

Implementation Method 1

a fixed bed disposed within the adsorber body comprising solid material capable of promoting adsorption with a gas stream

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2575997B1Integrated adsorber head and valve design and swing adsorption methods related thereto
Publication Date: 2021.06.30 EXXONMOBIL UPSTREAM RESEARCH COMPANY(US)
  • EP2575997B1 patent drawingFigure 1
  • EP2575997B1 patent drawingFigure 2
  • EP2575997B1 patent drawingFigure 3

AI summary

An adsorber with minimal dead volume especially suited to reverse-flow applications comprises: a) an adsorber body; b) a first head engaged with said adsorber body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the adsorber body. The adsorber is especially suited for use in a process for swing adsorption separation processes.