Integrated Aromatics Formation and Methylation Reactor

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Solution Overview

Problem

Current processes for converting non-aromatic hydrocarbons to aromatic hydrocarbons, such as para-xylene, are inefficient due to low activity of alkane compounds and require separate reactors and processing trains for aromatization and methylation, leading to increased costs and complexity.

Innovation Solution

Integration of light ends processing trains from aromatic formation and methylation processes allows for the partial processing of qualitatively different light ends together, facilitating the recycle of non-aromatic hydrocarbons and reducing equipment footprint by combining cooling systems and using hydrogen for olefin saturation, thereby improving the overall yield and efficiency of para-xylene production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If separate reactors and processing trains are used for aromatization and methylation, then the conversion of non-aromatic hydrocarbons to aromatic hydrocarbons and subsequent methylation can be performed, but the equipment footprint and process complexity increase

Engineering Contradiction:
Improveconversion efficiencyVSAvoidequipment footprint
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent combines the aromatization reactor and methylation reactor into a single integrated reactor system. The reactor performs both the conversion of non-aromatic hydrocarbons to aromatic hydrocarbons and the subsequent methylation of aromatic hydrocarbons in sequence within the same reaction zone, eliminating the need for separate reactors and reducing equipment footprint while maintaining conversion efficiency

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The integrated reactor is designed to perform multiple functions: it acts as both an aromatization reactor for converting non-aromatic hydrocarbons to aromatic hydrocarbons and a methylation reactor for methylating the aromatic hydrocarbons. This multi-functional design reduces the number of processing trains required and simplifies the overall process configuration

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If separate processing trains are used for aromatization and methylation, then each process can be optimized independently, but the overall process cost and complexity increase

Engineering Contradiction:
Improveprocess optimizationVSAvoidprocessing train complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the processing trains for aromatization and methylation into a single integrated processing system. The integrated reactor combines both reaction functions, and the downstream separation train processes the combined effluent from both reactions, reducing the number of separate processing trains while maintaining the ability to optimize reaction conditions for both processes

Inventive Principle:
Principle #5Merging (Combining)

3Ease of operation

If light ends from aromatization and methylation are processed separately, then each stream can be treated independently, but the equipment footprint and processing complexity increase

Engineering Contradiction:
Improveindependent processingVSAvoidlight ends processing complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent combines the light ends processing from both the aromatization and methylation reactions into a single integrated light ends train. The effluent from the integrated reactor is processed through a unified separation and treatment system that handles the combined light ends stream, reducing equipment footprint and processing complexity while maintaining operational efficiency

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This integrated approach enhances the yield and efficiency of para-xylene production by reducing equipment complexity and costs, while maintaining the segregation of C8 aromatics streams to improve para-xylene separation, allowing for more efficient recycling of non-aromatic hydrocarbons and optimized use of refrigerants.

Implementation Method 1

an aromatic formation process for converting non-aromatic hydrocarbon to an aromatic product

Methodology Applied
Scientific EffectDehydroaromatization: Chemical Bonding

Implementation Method 2

methylating at least a portion of the aromatic product to produce a methylated product containing additional para-xylene

Methodology Applied
Scientific EffectMethylation: Chemical Bonding

Implementation Method 3

combining cooling systems

Methodology Applied
Scientific EffectHeat removal: Cooling

Implementation Method 4

using hydrogen for olefin saturation

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Data Source

PatentUS11377402B2Integrated aromatics formation and methylation
Publication Date: 2022.07.05 EXXONMOBIL CHEMICAL PATENTS INC
  • US11377402B2 patent drawing
  • US11377402B2 patent drawing
  • US11377402B2 patent drawing

AI summary

Systems and methods are provided for integration of an aromatic formation process for converting non-aromatic hydrocarbon to an aromatic product and subsequent methylating of a portion of the aromatic product to produce a methylated product, with improvements in the aromatic formation process and/or the methylation process based on integrating portions of the secondary processing trains associated with the aromatic formation process and the methylation process. The aromatic formation process and methylation process can be used, for example, for integrated production of specialty aromatics or gasoline blending components.