Integrated Isomerization and Reforming Process for Gasoline Blending

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Solution Overview

Problem

Modern refineries face challenges in blending gasoline due to excess reformate relative to isomerate, necessitating additional components, which complicates refinery operations and limits aromatic content in gasoline, especially in hydrocracking-based refineries focused on high distillate yields.

Innovation Solution

A method and system that combines isomerization and reforming processes in a single reaction zone configuration, where C5-C6 hydrocarbons are isomerized and C7+ hydrocarbons are reformed, with the reformed C7 hydrocarbons subsequently isomerized, allowing for direct blending of isomerate and reformate to produce gasoline.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If separate isomerization and reforming processes are used for C5-C6 and C7+ hydrocarbons, then product quality can be optimized, but device complexity and operational complexity increase

Engineering Contradiction:
Improveproduct qualityVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines separate isomerization and reforming processes into a single integrated reaction zone that simultaneously processes C5-C6 hydrocarbons through isomerization and C7+ hydrocarbons through reforming. This merging eliminates the need for separate reaction zones and reduces operational complexity while maintaining product quality through optimized reaction conditions and catalyst selection.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The integrated reaction zone performs multiple functions simultaneously: it acts as both an isomerization reactor for C5-C6 hydrocarbons and a reforming reactor for C7+ hydrocarbons. This multi-functional design allows a single unit to replace what would traditionally require separate dedicated units, simplifying the overall process configuration.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If excess reformate is produced relative to isomerate, then refinery productivity increases, but ease of operation decreases due to blending complications

Engineering Contradiction:
Improverefinery outputVSAvoidblending operation
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent adjusts reaction parameters including temperature, pressure, and catalyst composition within the integrated reaction zone to optimize the ratio of isomerate to reformate production. By controlling these parameters, the process produces balanced quantities of both products that are suitable for direct blending into finished gasoline, eliminating the operational complications associated with excess reformate.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If aromatic content in gasoline is limited to 35% max, then product quality meets specifications, but productivity decreases due to additional blending requirements

Engineering Contradiction:
Improvegasoline specification complianceVSAvoidgasoline production efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The integrated process produces isomerate and reformate in optimized proportions that allow direct blending to meet the 35% aromatic specification without requiring additional blending components. The reaction conditions are tuned to produce sufficient high-octane components while maintaining aromatic content within specification limits, achieving compliance efficiently.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies refinery operations by enabling direct blending of isomerate and reformate, optimizing hydrocarbon processing and reducing the need for additional components, thereby enhancing the efficiency of hydrocarbon isomerization and reforming processes.

Implementation Method 1

a first isomerization reaction zone configured to receive the first hydrocarbon feed stream and produce a first isomerization reaction zone effluent stream

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

a reforming zone configured to receive the second hydrocarbon stream and produce a reforming zone effluent stream

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10240097B2Methods and apparatuses for an integrated isomerization and platforming process
Publication Date: 2019.03.26 UOP LLC
  • US10240097B2 patent drawing

AI summary

The present disclosure generally relates to methods and systems for reforming and isomerizing hydrocarbons. More particularly, the present disclosure relates to a novel combination of two traditionally separate reforming and isomerization reaction zones. A first hydrocarbon stream comprising C5-C6 hydrocarbons is isomerized in a first isomerization zone. A second hydrocarbon stream comprising C7+ hydrocarbons is reformed thus producing a C7 hydrocarbon stream and a C8 hydrocarbon stream. The reformed C7 stream is then isomerized in a second isomerization zone.