Interconnect Barrier Stack for Low-k Adhesion and Diffusion Control

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Solution Overview

Problem

As semiconductor devices become denser and circuit elements smaller, resistance-capacitance (RC) delay time significantly impacts integrated circuit performance, necessitating the use of low-k dielectric materials to reduce RC delay.

Innovation Solution

The method involves forming a semiconductor device with a specific etch stop stack and dielectric layer structure, including a Group IV element-doped layer and a low-k dielectric layer, and using a surface treatment and inhibitor portions to control the deposition of barrier layers and conductive materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If low-k dielectric materials are used to reduce RC delay, then circuit performance is improved, but adhesion between conductive materials and dielectric layers deteriorates

Engineering Contradiction:
Improvecircuit performanceVSAvoidadhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

A barrier layer is introduced as an intermediary between the conductive material (e.g., copper) and the low-k dielectric material. This barrier layer prevents direct contact between the conductive material and the low-k dielectric, thereby preventing adhesion deterioration while maintaining the low RC delay benefit of the low-k dielectric material.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The barrier layer is deposited in advance before the conductive material is formed, creating a protective interface that prevents harmful adhesion interactions between the conductive material and the low-k dielectric material from occurring in the first place.

Inventive Principle:
Principle #9Preliminary anti-action

2Ease of manufacture

If conductive materials are deposited directly on dielectric layers, then manufacturing process is simplified, but metal diffusion into dielectric layers occurs

Engineering Contradiction:
Improveprocess complexityVSAvoiddielectric layer composition
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The barrier layer serves as a diffusion barrier, preventing metal atoms from the conductive material from diffusing into the low-k dielectric material, thereby maintaining the compositional stability of the dielectric layer while allowing the manufacturing process to remain relatively simple.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If etch stop layers are added to control deposition, then adhesion and diffusion control are improved, but device complexity increases

Engineering Contradiction:
Improveadhesion and diffusion controlVSAvoidlayer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The barrier layer performs multiple functions simultaneously: it acts as an adhesion promoter between the conductive material and the low-k dielectric material, serves as a diffusion barrier to prevent metal contamination, and provides a controlled interface for subsequent deposition processes. This multi-functionality reduces the need for separate etch stop layers, thereby limiting the increase in device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces RC delay, enhances the stability and adhesion of interconnects, and improves the overall performance of semiconductor devices by preventing metal diffusion and ensuring good contact between conductive features and dielectric layers.

Implementation Method 1

surface treatment to modify the surface energy of the dielectric layer

Methodology Applied
Scientific EffectSurface energy modification: Surface Tension

Implementation Method 2

barrier layer formed on the dielectric layer... preventing metal diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS20250105057A1Semiconductor device and method of forming the same
Publication Date: 2025.03.27 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250105057A1 patent drawing
  • US20250105057A1 patent drawing
  • US20250105057A1 patent drawing

AI summary

An interconnect structure includes a first conductive feature, a first dielectric layer a first etch stop layer, a second etch stop layer, a second dielectric layer, and a second conductive feature. The first etch stop layer is disposed over the first conductive feature and the first dielectric layer. The second etch stop layer is disposed on the first etch stop layer. The second dielectric layer is disposed on the second etch stop layer. The second conductive feature includes a first conductive layer and a first barrier layer. The first conductive layer extends through the second dielectric layer, the second and the first etch stop layers to contact to the first conductive feature. The first barrier layer is sandwiched between the first conductive layer and the second dielectric layer, the first conductive layer and the second etch stop layer, and between the first conductive layer and the first etch stop layer.