Interconnect Structures Nucleation Treatment

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Solution Overview

Problem

The semiconductor industry faces challenges in forming interconnect structures with reduced resistance and increased process windows due to the need for seed layers and high resistance metal-containing barrier layers, which limit the efficiency and complexity of scaling down in IC manufacturing.

Innovation Solution

The method involves forming a dual damascene interconnect structure without a seed layer or metal-containing barrier layer, using a nucleation enhancement treatment to enable bottom-up and conformal deposition of conductive fill materials directly on dielectric surfaces, thereby reducing resistance and increasing process windows.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If seed layers and metal-containing barrier layers are used in interconnect structures, then adhesion and protection are improved, but resistance increases and process complexity worsens

Engineering Contradiction:
ImproveadhesionVSAvoidresistance
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent removes the seed layer and metal-containing barrier layer from the interconnect structure, retaining only the dielectric layer and conductive fill material. This extraction eliminates the high resistance and complexity associated with multiple layers while maintaining adhesion through the dielectric layer alone.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a composite structure consisting of a dielectric layer combined with conductive fill material (such as copper or cobalt). This composite approach replaces traditional metal barrier layers with a dielectric-conductive combination that achieves both adhesion and low resistance properties.

Inventive Principle:
Principle #40Composite materials

2Strength

If seed layers and metal-containing barrier layers are used, then structural integrity is improved, but device complexity and processing steps increase

Engineering Contradiction:
Improvestructural integrityVSAvoidprocessing steps
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent extracts and removes the seed layer and metal-containing barrier layer, reducing the interconnect structure to essential components only. This simplification decreases device complexity and reduces the number of processing steps required for fabrication.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Instead of adding multiple protective layers to achieve structural integrity, the patent inverts the approach by using a minimal structure with the dielectric layer serving multiple functions. The dielectric layer provides both mechanical support and adhesion, eliminating the need for separate barrier and seed layers.

Inventive Principle:
Principle #13The other way round (Inversion)

3Reliability

If conventional interconnect structures with multiple layers are used, then adhesion is improved, but RC delay increases due to higher resistance

Engineering Contradiction:
ImproveadhesionVSAvoidRC delay
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent removes the high-resistance seed layer and metal-containing barrier layer, eliminating the primary sources of resistance that contribute to RC delay. The resulting structure has lower resistance while maintaining adhesion through the dielectric layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs a composite of dielectric layer and conductive fill material that achieves low resistance. The conductive fill material (copper or cobalt) provides excellent electrical conductivity, while the dielectric layer maintains adhesion, together reducing RC delay compared to traditional metal barrier structures.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the resistance of interconnect structures, decreases RC delay, and enhances processing throughput by allowing bottom-up deposition and conformal filling of trenches, making it suitable for advanced technology nodes like 20 nm and smaller.

Implementation Method 1

A nucleation enhancement treatment is performed on one or more exposed dielectric surfaces of the trench

Methodology Applied
Scientific EffectNucleation enhancement: Nucleation

Data Source

PatentUS20230154845A1Interconnect Structures
Publication Date: 2023.05.18 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20230154845A1 patent drawing
  • US20230154845A1 patent drawing
  • US20230154845A1 patent drawing

AI summary

Embodiments described herein relate generally to one or more methods for forming an interconnect structure, such as a dual damascene interconnect structure comprising a conductive line and a conductive via, and structures formed thereby. In some embodiments, an interconnect opening is formed through one or more dielectric layers over a semiconductor substrate. The interconnect opening has a via opening and a trench over the via opening. A conductive via is formed in the via opening. A nucleation enhancement treatment is performed on one or more exposed dielectric surfaces of the trench. A conductive line is formed in the trench on the one or more exposed dielectric surfaces of the trench and on the conductive via.