Interdigitated GdN-InN Neutron Detector for High Capture Efficiency

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Solution Overview

Problem

Current solid-state neutron detectors face challenges in achieving high sensitivity, compactness, and cost-effectiveness, especially in low flux environments and harsh conditions, due to limitations in neutron capture cross-sections and material scarcity, such as the rarity of helium-3, and mechanical/thermal instability of existing detectors.

Innovation Solution

The development of compact solid-state neutron detectors using interdigitated layers or micro/nano-column structures of materials with high neutron capture cross-sections, such as GdN and InN, integrated with a graded GaN/InGaN/InN layer and a capping ZrN layer, which enhances neutron absorption and charge transfer efficiency, and is fabricated using techniques like RF assisted DC magnetron co-sputtering and pulsed laser ablation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If thick layers of converter material (e.g., 10B) are used to increase neutron absorption, then neutron capture efficiency improves, but charged particles are absorbed within the converter material before reaching the semiconductor interface

Engineering Contradiction:
Improveneutron capture efficiencyVSAvoidcharge transfer efficiency
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The converter material layer is segmented into an interdigitated structure with alternating high-Z (e.g., 10B) and low-Z (e.g., 6Li) material regions. This segmentation allows neutrons to be absorbed throughout the layer volume while ensuring that charged particles generated in low-Z regions can reach the semiconductor interface, resolving the contradiction between neutron capture efficiency and charge transfer efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the converter material layer are assigned different material compositions optimized for their specific functions: high-Z materials (10B) in regions optimized for neutron absorption, and low-Z materials (6Li) in regions optimized for charged particle transmission. This local differentiation allows simultaneous optimization of both neutron capture and charge transfer efficiencies.

Inventive Principle:
Principle #3Local quality

2Device complexity

If conventional thin-film coated semiconductors are used, then device complexity is reduced, but neutron capture efficiency drops to very low levels (e.g., 1.3% for Mg2B14 on silicon)

Engineering Contradiction:
Improvefabrication simplicityVSAvoidneutron capture efficiency
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The converter material layer is constructed as a composite of multiple materials (e.g., 10B and 6Li) arranged in an interdigitated pattern, combining the high neutron capture cross-section of 10B with the favorable charged particle transmission properties of 6Li. This composite structure achieves high neutron capture efficiency while maintaining compatibility with semiconductor fabrication processes.

Inventive Principle:
Principle #40Composite materials

3Measurement precision

If helium-3 gas tubes are used to achieve high detection efficiency (up to 80%), then neutron detection performance improves, but the devices become bulky and mechanically unstable

Engineering Contradiction:
Improvedetection efficiencyVSAvoidmechanical and thermal stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The mechanical gas-filled tube system is replaced with a solid-state semiconductor device with an integrated converter material layer. This substitution eliminates the mechanical and thermal instability inherent in gas tubes while achieving comparable or superior detection efficiency through the optimized interdigitated converter structure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Measurement precision

If 6LiF:ZnS(μg) scintillators with PMTs are used to achieve high sensitivity, then neutron detection efficiency improves, but the device footprint increases and portability becomes difficult

Engineering Contradiction:
Improveneutron detection sensitivityVSAvoiddevice footprint
Core Design Contradiction:
Measurement precisionVSVolume of moving object

Solution Approach 1:

The bulky PMT-based scintillation detection system is replaced with a compact solid-state semiconductor device. The semiconductor detector directly converts neutron-induced charged particles into electrical signals, eliminating the need for optical coupling and PMT components, thereby achieving high sensitivity in a portable form factor.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in highly efficient, compact, and cost-effective neutron detectors capable of operating in harsh environments, with improved neutron detection efficiency and stability, alleviating the limitations of existing technologies.

Implementation Method 1

the neutron capture cross-section of silicon-28 isotope is ~1 barn (10−24 cm2), compared to boron-10 (10B), which is close to 3,840 barns

Methodology Applied
Scientific EffectNeutron absorption: Absorption (physical)

Implementation Method 2

If for example, 10B is used as the converter material to a semiconductor type neutron detector, alpha particles (1.47 MeV) and lithium-7 (7Li) (0.84 MeV) particles are generated

Methodology Applied
Scientific EffectCharged particle generation: Nuclear Fission

Implementation Method 3

alpha particles (1.47 MeV) and lithium-7 (7Li) (0.84 MeV) particles are generated, which travel through the semiconductor and generate electron-hole pairs that are collected by the contacts

Methodology Applied
Scientific EffectElectron-hole pair generation: Photoelectric Effect

Implementation Method 4

fabricated using techniques like RF assisted DC magnetron co-sputtering and pulsed laser ablation

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 5

fabricated using techniques like RF assisted DC magnetron co-sputtering and pulsed laser ablation

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS9671507B2Solid-state neutron detector device
Publication Date: 2017.06.06 UNIV HOUSTON SYST
  • US9671507B2 patent drawing
  • US9671507B2 patent drawing
  • US9671507B2 patent drawing

AI summary

The structure and methods of fabricating a high efficiency compact solid state neutron detector based on III-Nitride semiconductor structures deposited on a substrate. The operation of the device is based on absorption of neutrons, which results in generation of free carriers.