Interfacial Dopant Caps for Electromigration Resistance in Damascene Interconnects

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Solution Overview

Problem

As integrated circuit (IC) devices miniaturize, electromigration failures increase due to high current densities causing metal atom migration and void formation in interconnects, particularly at the 45 nm technology node and beyond, where copper interconnects face significant reliability issues despite having better electromigration resistance than aluminum.

Innovation Solution

The formation of thin protective caps at the interface between metal lines and dielectric diffusion barrier layers using dopant elements like boron, aluminum, titanium, etc., which diffuse into the metal to form solid solutions, alloys, or compounds, reducing metal atom migration without significantly increasing interconnect resistance. These caps are created by depositing a dopant source layer, modifying it to form a passivated layer, and allowing the dopant to react with the metal, controlling the cap thickness and diffusion process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of moving object

If interconnect dimensions are decreased during miniaturization, then device integration density is improved, but electromigration failure probability increases due to higher current densities

Engineering Contradiction:
Improveinterconnect dimensionsVSAvoidelectromigration failure probability
Core Design Contradiction:
Area of moving objectVSReliability

Solution Approach 1:

The patent applies local quality by creating a protective cap layer at the specific location where electromigration is most severe (the metal/dielectric interface). This cap layer has different properties than the bulk metal, providing localized protection against atom migration without affecting the overall interconnect dimensions or current carrying capacity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The protective cap layer acts as an intermediary between the metal interconnect and the dielectric material. This intermediate layer prevents direct interaction that leads to electromigration, serving as a buffer that reduces metal atom migration while allowing the interconnect to maintain its electrical function.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If protective cap layers are formed at the metal/dielectric interface, then electromigration resistance is improved, but interconnect resistance increases

Engineering Contradiction:
Improveelectromigration resistanceVSAvoidinterconnect resistance
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies partial action by forming a thin protective cap layer that provides sufficient electromigration protection without excessive thickness. This partial protection approach ensures that the cap layer is thick enough to prevent metal atom migration but thin enough to minimize its impact on electrical resistance and energy loss.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method improves electromigration performance and adhesion at the metal/dielectric interface, maintaining low interconnect resistance while enhancing the reliability of IC devices by effectively reducing metal atom migration and void formation.

Implementation Method 1

dopant elements like boron, aluminum, titanium, etc., which diffuse into the metal to form solid solutions, alloys, or compounds

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

allowing the dopant to react with the metal, controlling the cap thickness and diffusion process

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS7799671B1Interfacial layers for electromigration resistance improvement in damascene interconnects
Publication Date: 2010.09.21 NOVELLUS SYSTEMS INC
  • US7799671B1 patent drawing
  • US7799671B1 patent drawing
  • US7799671B1 patent drawing

AI summary

Protective caps residing at an interface between metal lines and dielectric diffusion barrier (or etch stop) layers are used to improve electromigration performance of interconnects. Protective caps are formed by depositing a source layer of dopant-generating material (e.g., material generating B, Al, Ti, etc.) over an exposed copper line, converting the upper portion of the source layer to a passivated layer (e.g., nitride or oxide) while allowing an unmodified portion of a dopant-generating source layer to remain in contact with copper, and, subsequently, allowing the dopant from the unmodified portion of source layer to controllably diffuse into and/or react with copper, thereby forming a thin protective cap within copper line. The cap may contain a solid solution or an alloy of copper with the dopant.