Interference Coating Adhesion via Silicon Oxide Mediator

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing ophthalmic lenses with interference coatings face issues of poor adhesion, cracking due to mechanical deformations and temperature stresses, leading to obstructed vision and reduced durability, especially when high refractive index layers are deposited directly on low refractive index layers formed from organosilicon compounds.

Innovation Solution

The solution involves modifying the high refractive index layer by incorporating an organosilicon compound during deposition, using an ion source to create a hybrid layer with improved adhesion, and inserting a silicon oxide layer to enhance the interface between layers, resulting in a multilayer interference coating with improved thermomechanical properties and optical performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a high refractive index layer is deposited directly on a low refractive index layer formed from organosilicon compounds, then the optical performance is improved, but the adhesion between layers deteriorates and cracking occurs

Engineering Contradiction:
Improveoptical performanceVSAvoidadhesion between layers
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent introduces an intermediate layer comprising silicon oxide deposited between the low refractive index layer (formed from organosilicon compounds) and the high refractive index layer. This intermediate layer acts as a mediator that improves adhesion between the two layers, preventing cracking while maintaining optical performance. The silicon oxide layer creates a gradual transition in material properties, reducing the abrupt interface that causes adhesion failure.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Illumination intensity

If mineral interference coatings are used to prevent reflections, then optical performance is improved, but the coatings become prone to cracking during mechanical deformations and temperature fluctuations

Engineering Contradiction:
Improveanti-reflective performanceVSAvoidresistance to cracking
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The patent employs a composite multilayer structure combining organic/organosilicon compounds with inorganic metal oxides. The interference coating consists of alternating layers of low refractive index (from organosilicon compounds) and high refractive index (from metal oxides like TiO2, ZrO2, Ta2O5). This composite structure leverages the advantages of both material types: the organosilicon layers provide flexibility and adhesion, while the metal oxide layers provide hardness and optical performance, resulting in a coating that resists cracking under mechanical and thermal stress.

Inventive Principle:
Principle #40Composite materials

3Temperature

If the interference coating is made from purely inorganic materials, then thermal resistance is improved, but adhesion to the substrate and between layers deteriorates

Engineering Contradiction:
Improvethermal resistanceVSAvoidadhesion
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies local quality by using different material compositions in different layers of the interference coating. The low refractive index layers are formed from organosilicon compounds which provide excellent adhesion properties, while the high refractive index layers are formed from inorganic metal oxides that provide thermal resistance and optical performance. Each layer is optimized for its specific function, creating a heterogeneous structure where adhesion and thermal resistance are both satisfied in their respective locations.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in lenses with enhanced resistance to cracking, deformation, and abrasion, maintaining high refractive index and transparency, while ensuring good adhesion and durability, thus addressing the adhesion and durability issues of traditional coatings.

Implementation Method 1

layer A obtained by vacuum deposition, assisted by an ion source, of at least one organosilicon compound A

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

vacuum deposition, assisted by an ion source

Methodology Applied
Scientific EffectIon Beam: Ion Beam

Implementation Method 3

layer B obtained by vacuum deposition, assisted by an ion source, of at least one metal oxide and at least one organosilicon compound B

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 4

vacuum deposition, assisted by an ion source

Methodology Applied
Scientific EffectIon Beam: Ion Beam

Implementation Method 5

layer C comprising a silicon oxide and having a thickness less than or equal to 15 nm

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentEP3332273B1Item having optimized adhesive properties and comprising a silicon organic layer
Publication Date: 2022.10.05 ESSILOR INTERNATIONAL(COMPAGNIE GENERALE D OPTIQUE)
  • EP3332273B1 patent drawing
  • EP3332273B1 patent drawing
  • EP3332273B1 patent drawing

AI summary

The invention relates to an item including a substrate having at least one main surface coated with an interference coating including: a layer A that has a refractive index less than or equal to 1.65 and is obtained via vacuum deposition assisted by an ion source made of at least one organosilicon compound A and making direct contact with said layer A, a layer B that has a refractive index greater than 1.65 and is obtained via vacuum deposition assisted by an ion source made of at least one metal oxide and at least one organosilicon compound B, said layer B containing at least one metal oxide having a refractive index greater than or equal to 1.8, or a layer C that includes a silicon oxide, has a thickness less than or equal to 15 nm, and makes direct contact with a layer E that includes at least one metal oxide having a refractive index greater than or equal to 1.8.