Internal circulation type clathrate hydrate-based cold storage system and method

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Solution Overview

Problem

Existing cold storage systems suffer from slow hydrate nucleation and low energy storage conversion rates.

Innovation Solution

An internal circulation type clathrate hydrate-based cold storage system with a gas disturbance generator, crystallization promoting assembly, and a coil in the hydrate-based cold storage tank to induce rapid nucleation, combined with a chiller and heat exchanger for efficient energy storage and supply.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional cold storage systems are used, then the system structure is simple, but the hydrate nucleation speed is slow and energy storage conversion rate is low

Engineering Contradiction:
Improveenergy storage conversion rateVSAvoidsystem structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces a gas disturbance generator as an intermediary device that produces gas bubbles to disturb the solution and accelerate hydrate nucleation. The gas bubbles act as mediators between the cooling system and the hydrate formation process, enhancing mass and heat transfer without requiring direct modification of the core cooling mechanism.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces conventional mechanical stirring methods with a gas disturbance mechanism. Instead of using mechanical agitators that require direct contact with the solution, the system uses gas injection to create natural convection and disturbance, achieving nucleation acceleration through fluid dynamics rather than mechanical force.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If hydrate nucleation is accelerated using external methods, then the energy storage conversion rate improves, but the system complexity increases

Engineering Contradiction:
Improvenucleation speedVSAvoidnucleation promotion system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The gas disturbance generator is designed to operate autonomously within the system, using the existing pressure differential and solution flow to generate gas bubbles that promote nucleation. The system self-regulates the disturbance intensity based on operating conditions, reducing the need for external control mechanisms and complex regulation systems.

Inventive Principle:
Principle #25Self-service

3Temperature

If the cold storage system operates continuously, then the cooling capacity is maintained, but the energy consumption increases

Engineering Contradiction:
Improvecooling capacityVSAvoidenergy consumption
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The patent utilizes the phase transition of water to hydrate form as the primary cooling mechanism. This phase change process absorbs and releases large amounts of latent heat, enabling the system to maintain cooling capacity during continuous operation without proportionally increasing energy consumption, as the phase transition itself provides thermal regulation.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves energy storage conversion rate and cooling capacity by accelerating hydrate nucleation and utilizing latent heat, enabling high efficiency, energy savings, and stable operation for continuous cold energy supply.

Implementation Method 1

the gas disturbance generator creates gas disturbance on the hydrate-based cold storage working medium in the hydrate-based cold storage tank, so as to induce the hydrate nucleation and accelerate energy storage

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 2

a coil is arranged in the hydrate-based cold storage tank and immersed in the hydrate-based cold storage working medium

Methodology Applied
Scientific EffectHeat exchanger: Heat Exchanger

Implementation Method 3

utilizing latent heat, enabling high efficiency, energy savings, and stable operation for continuous cold energy supply

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 4

a chiller, a first solution pump, a first flow meter... the outlet end of the chiller is in communication with an inlet of the heat exchanger

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS12410965B2Internal circulation type clathrate hydrate-based cold storage system and method
Publication Date: 2025.09.09 DALIAN UNIV OF TECH
  • US12410965B2 patent drawing
  • US12410965B2 patent drawing
  • US12410965B2 patent drawing

AI summary

A cold storage system and method are provided. The cold storage system includes a chiller, a hydrate-based cold storage tank, a gas disturbance generator, a concentration detector, a heat exchanger, a direct-current power supply and circuit controller, and a system monitor. Chiller provides a secondary refrigerant at a low temperature. The secondary refrigerant flows through a coil in the hydrate-based cold storage tank for a heat exchange. The gas disturbance generator induces hydrate nucleation. The concentration detector monitors a concentration of a hydrate solution in real time. The heat exchanger is equipped with a finned tube heat exchanger with a fan, to improve the cold supply efficiency of the cold storage system. The system monitor monitors a state change of the system in real time through a set of temperature-pressure sensor modules. Several cold energy supply modes can be realized in the present disclosure by adjusting opening/dosing of valves.