Intumescent Coating Cold Flexibility via Low-MW Polymer

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Solution Overview

Problem

Existing intumescent coating systems face limitations in cold flexibility, impact resistance, and processing efficiency, particularly due to the need for complex manufacturing processes and restricted freedom in formulating thick layers and foam height control, with prior (meth)acrylate-based systems requiring solvents and having limited low-temperature flexibility.

Innovation Solution

A novel intumescent reaction resin system characterized by a liquid polymer with a molecular weight between 1500 and 35,000 g/mol and a glass transition temperature below 15 °C, incorporating vinylic monomers and a blowing agent, which eliminates the need for solid (meth)acrylate polymer components and allows for improved metal adhesion, impact resistance, and controlled foaming.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-molecular-weight thermoplastic resins are used in intumescent coating systems, then fire protection performance is improved, but cold flexibility and impact resistance deteriorate at low temperatures

Engineering Contradiction:
Improvefire protection performanceVSAvoidcold flexibility and impact resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the molecular weight parameter of the polymer from high-molecular-weight (>100,000 g/mol) to low-molecular-weight (1,000-35,000 g/mol), which fundamentally alters the material's mechanical properties. This parameter change enables the resin to maintain flexibility and impact resistance at low temperatures while still providing fire protection, resolving the contradiction between fire performance and cold flexibility.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If solvent or water content is increased to improve application properties, then ease of application is improved, but drying time increases

Engineering Contradiction:
Improveapplication propertiesVSAvoiddrying time
Core Design Contradiction:
Ease of operationVSLoss of time

Solution Approach 1:

The patent extracts and eliminates the solvent or water component from the coating system, transitioning to a solvent-free formulation. This is achieved by using low-molecular-weight polymers that provide adequate application properties without requiring high solvent content, thereby eliminating the trade-off between application ease and drying time.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If sequential application from different sides is required to achieve complete coating, then coating completeness is improved, but processing time increases

Engineering Contradiction:
Improvecoating completenessVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent changes the viscosity parameter of the resin system by using low-molecular-weight polymers (1,000-35,000 g/mol), which provide optimal flow and leveling properties. This enables the coating to be applied in a single pass with complete coverage, eliminating the need for sequential application from different sides and significantly reducing processing time.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If solid (meth)acrylate polymer components are used, then fire protection performance is improved, but formulation freedom and manufacturing complexity worsen

Engineering Contradiction:
Improvefire protection performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the molecular weight parameter from high to low, transforming the material from a solid polymer requiring dissolution and pre-formulation to a liquid or low-viscosity resin that can be directly formulated. This parameter change simplifies the manufacturing process, eliminates the need for complex dissolution steps, and provides greater formulation freedom while maintaining fire protection performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves enhanced cold flexibility, improved metal adhesion, and increased degrees of freedom in additive formulation and foaming control, resulting in a more efficient and flexible intumescent coating with higher foam quality and reduced processing time.

Implementation Method 1

a liquid polymer with a mean molecular weight Mn between 1500 and 35,000 g/mol and a glass transition temperature below 15 °C

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 2

at least one component that acts as a blowing agent at temperatures above 200 °C

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 3

A coating produced from this intumescent formulation can be cured by polymerization

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentEP4143264B1Intumescent coating with improved cold flexibility
Publication Date: 2024.05.01 ROHM GMBH

AI summary

The present invention relates to a new reaction system for intumescent coating. Intumescent coatings are used, in particular, in fire control for metallic components, such as girders in building construction. In the event of fire, these coatings reactively expand, forming a fire-resistant insulating layer with low thermal conductivity around the metal girder and delaying a premature, thermally induced failure of this component by the insulation thus formed. The invention particularly relates to resin systems having improved low-temperature flexibility which ensure good adherence to metal and shock resistance even at low temperatures while avoiding the polymer components which are normally used in resin systems.