Ion Beam Carbonized Polymer Surfaces for Stable Charge Dissipation

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Solution Overview

Problem

Existing methods for creating charge dissipative surfaces on dielectric polymeric materials for space applications, such as antennas, fail to maintain low temperature dependence of surface resistivity while ensuring RF transparency and thermo-optical properties, leading to issues with electrostatic discharge and signal loss.

Innovation Solution

A method involving controlled ion beam treatment with rare gas ions to carbonize the surface of polymeric materials, forming a graded inorganic-organic transition layer with tunable surface resistivity and RF transparency, maintaining stability over a wide temperature range without compromising RF performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ion beam treatment is applied to create charge dissipative surfaces, then surface resistivity is reduced, but temperature dependence of surface resistivity increases

Engineering Contradiction:
Improvecharge dissipative performanceVSAvoidtemperature dependence of surface resistivity
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies parameter changes by precisely controlling ion beam treatment parameters (energy, fluence, gas type) to carbonize the polymer surface to a specific degree, creating a carbonized layer with controlled thickness and composition that achieves low temperature dependence of surface resistivity while maintaining charge dissipative properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure with a carbonized surface layer on the polymeric substrate. This composite structure combines the charge dissipative properties of carbonized material with the mechanical properties of the polymer, achieving both low surface resistivity and low temperature dependence

Inventive Principle:
Principle #40Composite materials

2Reliability

If surface carbonization is increased to reduce surface resistivity, then charge dissipative performance improves, but RF transparency decreases

Engineering Contradiction:
Improvecharge dissipative performanceVSAvoidRF loss
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies local quality by creating a thin carbonized surface layer (typically 1-100 nm) only at the surface of the polymer, leaving the bulk material unchanged. This localized modification provides charge dissipative functionality at the surface while maintaining RF transparency of the overall structure

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent precisely controls the degree of carbonization and layer thickness through ion beam parameters to achieve the optimal balance between charge dissipative performance and RF transparency, preventing excessive carbonization that would cause RF losses

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ion beam treatment is applied to modify surface properties, then surface resistivity is controlled, but thermo-optical properties are affected

Engineering Contradiction:
Improvesurface resistivity controlVSAvoidthermo-optical properties
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent controls ion beam treatment parameters (energy, fluence, temperature during treatment) to carbonize only the outermost surface layer while preserving the bulk polymer's thermo-optical properties, achieving surface resistivity control without affecting bulk composition

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves a stable charge dissipative surface with low temperature dependence of surface resistivity, maintaining RF transparency and robustness, capable of handling high RF power densities and resistant to space radiation, with minimal impact on thermal-optical properties.

Implementation Method 1

Ion implantation and/or ion bombardment is of growing interest in polymer science and engineering because of its demonstrated capability to modify the molecular structure, surface morphology and physical properties of polymers

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Implementation Method 2

the most common are the processes of polymer cross-linking or chain destruction due to energy transfer at atomic collisions and with following volatile final products release from the surface of the polymer, surface carbon content increase, called surface carbonization

Methodology Applied
Scientific EffectSurface carbonization: Pyrolysis

Data Source

PatentUS9174396B2Method of making charge dissipative surfaces of polymeric materials with low temperature dependence of surface resistivity and low RF loss
Publication Date: 2015.11.03 INTEGRITY TESTING LAB
  • US9174396B2 patent drawing
  • US9174396B2 patent drawing
  • US9174396B2 patent drawing

AI summary

A method of making a charge dissipative surface of a dielectric polymeric material with tunable (selectable) surface resistivity, comprises the step of controllably carbonizing the surface of the polymeric material in a vacuum environment by bombarding the polymeric surface with an ion beam of rare gas ions, the energy level of the ion source being from 2.5 to 30 keV, in the fluence range 1E16-5E17 ion/cm2 so as to reach a surface resistivity in the static dissipative range of 1E6 to 1E9 ohm/square at room temperature, with a temperature dependence of less than three orders of magnitude between −150° C. and +150° C., while having no impact on the RF performance of the material, with high RF power handling capability, and with tunable thermo-optical properties of the surface, including negligible impact on the thermo-optical properties and RF performance of the material, if required by applications.