Ion Beam Generator Using Insulating Nanowires

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Solution Overview

Problem

Existing ion beam generators face challenges in achieving homogeneous needle shapes and lengths, leading to inhomogeneous ion beams, and suffer from counterion accumulation and rapid degradation due to inefficient ion liquid circulation and frequent polarity inversions.

Innovation Solution

The ion beam generator features a substrate with nanofils extending towards the extraction electrode, forming an ionic liquid tablecloth, with nanofils made of insulating materials like gallium nitride, arranged in a specific pattern to enhance ion emission and reduce counterion accumulation, allowing for high-intensity ionic currents without frequent polarity reversals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional top-down engraving method is used to create needle arrays, then manufacturing process is established, but needle shape and length uniformity deteriorates

Engineering Contradiction:
Improvemanufacturing processVSAvoidneedle shape and length uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent inverts the traditional top-down engraving approach by using a bottom-up self-assembly method. Nanowires are grown epitaxially on a substrate to form the needle array, reversing the manufacturing paradigm from removal of material to addition of material. This inversion enables precise control of needle dimensions and uniformity while simplifying the manufacturing process.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent changes the fundamental parameters of the manufacturing approach by transitioning from mechanical engraving to epitaxial growth. By controlling growth parameters such as temperature, pressure, and precursor flows during molecular beam epitaxy or chemical vapor deposition, uniform nanowire arrays with precise dimensional control are achieved, resolving the contradiction between ease of manufacture and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conductive material needles are used for ion emission, then ion beam generation is enabled, but counterion accumulation on needle surface occurs

Engineering Contradiction:
Improveion beam generationVSAvoidcounterion accumulation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces an intermediary insulating layer (such as silicon dioxide or silicon nitride) between the conductive nanowire core and the ionic liquid. This intermediary layer prevents counterion accumulation on the needle surface while still allowing efficient ion emission, as the insulating layer can be made thin enough to permit electric field penetration and ion formation without direct contact between counterions and the conductive core.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs composite nanowire structures with a conductive core (e.g., gallium nitride or silicon) surrounded by an insulating shell. This composite material approach combines the advantages of both conductive and insulating materials, enabling efficient ion generation from the conductive core while preventing counterion accumulation on the insulating outer surface that contacts the ionic liquid.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If ionic liquid is not effectively circulated at needle tip, then device structure is simple, but ion liquid impoverishment and counterion saturation occur

Engineering Contradiction:
Improvedevice structureVSAvoidionic current intensity
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The patent enables self-service circulation of ionic liquid through capillary action. The nanoscale dimensions of the nanowire tips create capillary forces that automatically draw ionic liquid from the reservoir to the emission tips without requiring external pumps or complex circulation systems. This self-service mechanism maintains continuous ionic liquid supply and prevents counterion saturation while keeping the device structure simple.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes capillary hydraulic principles at the nanoscale to drive ionic liquid circulation. The narrow dimensions of the nanowire structures create capillary pressure gradients that automatically transport the ionic liquid from the bulk reservoir to the emission tips, enabling continuous refreshment of the ionic liquid at the emission site without external mechanical intervention.

Inventive Principle:
Principle #29Pneumatics and hydraulics

4Reliability

If polarity is frequently inverted to combat counterion accumulation, then counterion layer is reduced, but operational efficiency decreases

Engineering Contradiction:
Improvecounterion layer reductionVSAvoidoperational efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The insulating intermediary layer fundamentally changes the interaction between counterions and the needle structure. By preventing direct accumulation of counterions on the conductive core, the intermediary layer eliminates the need for frequent polarity inversions to remove counterion layers, thereby maintaining continuous high-efficiency operation without the operational interruptions associated with polarity switching.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The insulating shell is pre-applied to the nanowire core before operation, creating a permanent protective barrier against counterion accumulation. This preliminary action of coating the nanowires with insulating material prevents the counterion accumulation problem from occurring in the first place, eliminating the need for corrective polarity inversion operations during device operation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in stable, high-intensity ion beams with prolonged operational efficiency, reduced counterion accumulation, and improved longevity by maintaining a thin layer of ion liquid on nanofils, promoting effective ion emission and preventing degradation.

Implementation Method 1

apply a tension between said needle, or emission electrode, and another so-called extraction electrode. The extraction tension generates an emission of the ions by a field evaporation mechanism.

Methodology Applied
Scientific EffectField evaporation mechanism: Electric Field

Implementation Method 2

The electric field applied to ionic liquid leads to its deformation in the form of a conical meniscus called Cône de Taylor

Methodology Applied
Scientific EffectTaylor cone formation: Electric Field

Implementation Method 3

The plurality of nanofils and the substrate are electrically insulating

Methodology Applied
Scientific EffectElectrical insulation: Dielectric

Data Source

PatentEP3679597B1Ion beam generator with nanowires
Publication Date: 2023.03.01 CENT NAT DE LA RECH SCI (C N R S)
  • EP3679597B1 patent drawingFigure 1~4
  • EP3679597B1 patent drawingFigure 5~7
  • EP3679597B1 patent drawingFigure 8

AI summary

The present invention relates to an ion beam generator (10), including an emission electrode (12), an extraction electrode (14), and an electricity generator (16). The emission electrode comprises a substrate (20) and a plurality of nanowires (24) extending away from said substrate, substantially towards the extraction electrode, said nanowires having a length of 50 nm to 50 μm. The emission electrode comprises a source of ions comprising a sheet (42) of ionic liquid (40) formed on the substrate and at least partially immersing the nanowires. Said nanowires and the substrate are electrically insulating or semiconducting, the electricity generator (16) being connected to the sheet (42) of ionic liquid. The emission electrode is thus capable of sending ion beams from the ionic liquid to the extraction electrode.