Ion Deflector Electrostatic Fields Mass Spectrometer Sensitivity

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Solution Overview

Problem

Current ion optics systems in mass spectrometers face limitations in measurement sensitivity at certain ion energy levels, particularly due to the inability to effectively guide and focus ions within the device.

Innovation Solution

An ion deflector system utilizing multiple electrostatic fields generated by chargeable elements with adjustable bias voltage potentials is introduced, allowing for precise manipulation and focusing of ions within three-dimensional space by creating electric monopole fields, enabling ions to be steered and focused towards specific spatial regions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional ion optics systems are used to guide ions in mass spectrometers, then the basic ion guidance function is achieved, but measurement sensitivity is limited at certain ion energy levels

Engineering Contradiction:
Improvemeasurement sensitivityVSAvoidion optics system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The ion deflector is segmented into multiple independently controllable electrostatic elements (first and second deflectors, each with multiple electrodes). This segmentation allows precise control of ion trajectories through coordinated voltage adjustment of individual elements, improving measurement sensitivity while maintaining manageable system complexity through modular design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The ion optics system employs dynamic voltage control where voltages applied to electrostatic elements are adjusted based on ion energy levels and desired deflection angles. This dynamic adaptability enables the system to optimize performance across different operating conditions, resolving the sensitivity limitation at certain energy levels without requiring a completely different system architecture.

Inventive Principle:
Principle #15Dynamics

2Measurement precision

If multiple electrostatic fields are used to deflect and focus ions precisely, then measurement sensitivity and ion control are improved, but the device complexity increases

Engineering Contradiction:
Improveion focusing precisionVSAvoidelectric field inducer complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The electrostatic elements serve multiple functions: they generate deflecting fields, focusing fields, and can be configured to create combined deflection-focusing patterns. The same set of electrodes can operate in different modes depending on voltage configuration, reducing the need for separate specialized components and managing complexity while maintaining precise ion control capability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system achieves precise ion manipulation by changing electrical parameters (voltages) rather than physical configurations. By adjusting voltage magnitudes and polarities on existing electrostatic elements, the system can dynamically reconfigure field patterns for different deflection and focusing requirements, avoiding the complexity of mechanically reconfigurable structures.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional ion guidance arrangements are used, then the mass spectrometer structure is simpler, but the ability to eliminate collisional cells is limited

Engineering Contradiction:
Improveoverall instrument structureVSAvoidcollisional cell elimination capability
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent replaces mechanical collisional cell structures with an electrostatic field-based ion guidance system. The multiple electrostatic deflectors and focusers provide the necessary ion trajectory control and filtering functions that traditionally required physical collisional cells, thereby eliminating or reducing mechanical components while maintaining or improving instrument versatility.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enhances measurement sensitivity by selectively deflecting and focusing ions, reducing unwanted particles and potentially eliminating the need for collisional cells, while allowing for more compact and flexible mass spectrometer designs.

Implementation Method 1

an electric field inducer arranged so as to establish more than one electrostatic field capable of deflecting ions travelling substantially along a first intended path of travel so as to travel substantially along a second intended path of travel

Methodology Applied
Scientific EffectElectrostatic field: Electric Field

Implementation Method 2

capable of deflecting ions travelling substantially along a first intended path of travel so as to travel substantially along a second intended path of travel

Methodology Applied
Scientific EffectIon deflection: Lorentz Force

Implementation Method 3

Each of the chargeable elements is arranged with a voltage source so that they each exhibit either a positive or negative bias voltage potential... the electric field produced is an electric monopole field

Methodology Applied
Scientific EffectElectric monopole field: Electric Field

Implementation Method 4

capable of causing a flow of ions travelling along a first of said axes of travel to be focused toward a spatial region of intended focus

Methodology Applied
Scientific EffectIon focusing: Electrostatic Lens

Data Source

PatentEP2828881B1An ion deflector for a mass spectrometer
Publication Date: 2018.05.02 ANATYTIK JENA AG
  • EP2828881B1 patent drawingFigure 1
  • EP2828881B1 patent drawingFigure 2
  • EP2828881B1 patent drawingFigure 3

AI summary

There is provided an ion deflector for use with a mass spectrometer for directing a flow of ions between two distinct axes of travel. The ion deflector includes an electric field inducer arranged so as to establish at least one electrostatic field capable of deflecting ions travelling substantially along a first intended path of travel so as to travel substantially along a second intended path of travel.