Variable-Section Ion Guide for Wide m/z Range and Low Contamination

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Solution Overview

Problem

Existing ion guides face issues with a reduced m/z range of ions passing through due to contamination and a complex structure, leading to performance degradation.

Innovation Solution

An ion guide design featuring varying cross-sectional areas of multipole and axial field electrodes from inlet to outlet, with plate-shaped electrodes and controlled voltage application to prevent contamination and focus ions efficiently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Force

If an electrode is inserted into a gap between rod electrodes to generate an axial electric field, then an axial electric field can be generated, but the structure becomes complicated and the electrode surface area becomes small, leading to contamination by neutral droplets

Engineering Contradiction:
Improveaxial electric fieldVSAvoidstructure complexity
Core Design Contradiction:
ForceVSDevice complexity

Solution Approach 1:

The patent combines the axial field electrode with the multipole electrode structure by making the axial field electrode extend along the center axis within the multipole electrode assembly. This integration eliminates the need for separate inserted electrodes while maintaining the axial electric field generation capability, thereby simplifying the overall structure and reducing contamination risks.

Inventive Principle:
Principle #5Merging (Combining)

2Force

If an electrode is inserted into a gap between rod electrodes to generate an axial electric field, then an axial electric field can be generated, but the electrode surface area becomes small, leading to contamination by neutral droplets

Engineering Contradiction:
Improveaxial electric fieldVSAvoidcontamination resistance
Core Design Contradiction:
ForceVSReliability

Solution Approach 1:

The patent extends the axial field electrode along the center axis in the longitudinal dimension of the ion guide, transforming it from a small inserted element into a long continuous electrode. This dimensional extension significantly increases the electrode surface area, enabling it to better resist contamination from neutral droplets while maintaining axial electric field generation.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Force

If rod electrodes are inclined to apply an axial electric field, then an axial electric field can be generated, but the m/z range of ions that can pass through decreases

Engineering Contradiction:
Improveaxial electric fieldVSAvoidm/z range
Core Design Contradiction:
ForceVSAdaptability or versatility

Solution Approach 1:

The patent applies different functional qualities to different regions: the multipole electrodes generate radial confinement fields while the centrally positioned axial field electrode generates the axial electric field. This localized functional differentiation allows independent optimization of each field's characteristics, enabling wide m/z range transmission while maintaining effective axial field generation without electrode inclination.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ion guide achieves a wide m/z range transmission with reduced contamination, efficient ion focusing, and noise reduction, while maintaining a simple structure.

Implementation Method 1

a multipole electrode for forming a multipole electric field

Methodology Applied
Scientific EffectMultipole electric field: Electric Field

Implementation Method 2

an axial field electrode for forming an axial electric field

Methodology Applied
Scientific EffectAxial electric field: Electric Field

Data Source

PatentEP4579714A1Ion guide, and mass spectrometry device provided with same
Publication Date: 2025.07.02 HITACHI HIGH TECH CORP
  • EP4579714A1 patent drawingFigure 1
  • EP4579714A1 patent drawingFigure 2A
  • EP4579714A1 patent drawingFigure 2B

AI summary

In order to achieve an ion guide that has a simple structure, is resistant to contamination, and provides a wide m/z range of ions that can pass through the ion guide, the present disclosure proposes an ion guide into which ions are introduced and which is configured to focus and discharge the ions, the ion guide including a multipole electrode for forming a multipole electric field, and an axial field electrode for forming an axial electric field. The cross-sectional area perpendicular to the center axis of the ion guide of at least one of the multipole electrode or the axial field electrode varies from an inlet to an outlet of the ion guide (see FIG. 2A).