Ion-Implanted Film Layer for Lower-Dose EUV Photoresist Patterning

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Solution Overview

Problem

Conventional EUV lithography processes require high energy and long exposure times, making it challenging to reliably form submicron and smaller features in semiconductor devices, and there is a need for a method to reduce EUV dose and energy usage.

Innovation Solution

The method involves implanting a dielectric film layer with ions, such as iodine and indium, beneath a metal oxide photoresist, which generates secondary electrons to reduce EUV dose and energy requirements, allowing for more efficient patterning and increased throughput.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional EUV lithography process is used, then submicron features can be formed, but high energy and long exposure time are required

Engineering Contradiction:
Improvefeature formationVSAvoidEUV dose
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent applies preliminary action by implanting ions (such as iodine or indium) into the hardmask layer before the EUV lithography exposure step. This pre-treatment modifies the hardmask properties to enhance secondary electron generation during subsequent EUV exposure, thereby reducing the required EUV dose and energy consumption while maintaining feature formation capability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes physical parameters of the hardmask layer by introducing ion implantation with specific energies (e.g., 1-10 keV) and doses (e.g., 1E14-1E16 ions/cm²). This modifies the hardmask's electronic structure and secondary electron yield, enabling reduced EUV dose requirements while preserving submicron feature formation precision

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If conventional EUV lithography process is used, then submicron features can be formed, but long exposure time is required

Engineering Contradiction:
Improvefeature formationVSAvoidexposure time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The ion implantation into the hardmask layer is performed as a preliminary step before EUV exposure. This pre-modification of the hardmask enhances secondary electron generation efficiency during exposure, allowing the same patterning quality to be achieved in shorter exposure times

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

By changing the physical state of the hardmask through ion implantation (introducing defects, modifying band structure), the patent increases the secondary electron yield per incident EUV photon, thereby reducing the total exposure time needed to achieve the required manufacturing precision

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If metal oxide photoresist is used, then patterning can be achieved, but significant EUV energy is consumed

Engineering Contradiction:
ImprovepatterningVSAvoidEUV energy
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent introduces the ion-implanted hardmask layer as an intermediary between the EUV source and the metal oxide photoresist. This intermediate layer acts as a secondary electron generator that amplifies the effective exposure of the photoresist, reducing the direct EUV energy burden on the photoresist while maintaining patterning fidelity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves a 15%-30% reduction in EUV dose and improves the efficiency of the EUV lithography process by accurately controlling ion concentration and depth, enhancing the formation of submicron features in semiconductor devices.

Implementation Method 1

implanting the film layer with ions

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

implanting the film layer with ions... which generates secondary electrons to reduce EUV dose and energy requirements

Methodology Applied
Scientific EffectSecondary electron generation: Photoelectric Effect

Data Source

PatentUS20240379376A1Implant into EUV metal oxide photoresist module to reduce EUV dose
Publication Date: 2024.11.14 APPLIED MATERIALS INC
  • US20240379376A1 patent drawing
  • US20240379376A1 patent drawing
  • US20240379376A1 patent drawing

AI summary

Disclosed herein are approaches for reducing EUV dose during formation of a patterned metal oxide photoresist. In one approach, a method may include providing a stack of layers atop a substrate, the stack of layers comprising a film layer, and implanting the film layer with ions. The method may further include depositing a metal oxide photoresist atop the film layer, and patterning the metal oxide photoresist.