Ion-Implanted Hard Mask for ILD Etch Protection

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Solution Overview

Problem

As semiconductor devices continue to reduce minimum feature sizes for increased integration density, the oxide material used in interlayer dielectric layers is susceptible to etching during transistor fabrication, leading to damage of underlying source/drain regions and poor device performance.

Innovation Solution

A hard mask is formed over the interlayer dielectric, followed by an ion implantation and annealing process to improve adhesion, reduce etching rate, and increase density, thereby protecting the ILD and reducing manufacturing defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ion implantation and annealing process is performed on the hard mask, then adhesion and density are improved and etching rate is reduced, but the manufacturing process complexity increases

Engineering Contradiction:
Improvehard mask effectivenessVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The ion implantation and annealing process is performed on the hard mask before the oxide etching process to pre-enhance its protective properties. This preliminary treatment ensures the hard mask has optimal adhesion, density, and etching resistance before it is needed to protect the ILD during subsequent etching operations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The ion implantation process changes the physical and chemical parameters of the hard mask material by introducing dopant atoms, which modifies its etching rate and adhesion properties. The subsequent annealing process further adjusts these parameters by healing implantation damage and enhancing material density, thereby optimizing the hard mask's protective effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If minimum feature sizes are reduced to increase integration density, then more components can be integrated, but the oxide material becomes more susceptible to etching damage

Engineering Contradiction:
Improveintegration densityVSAvoidetching susceptibility
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The hard mask undergoes ion implantation and annealing treatment in advance to create a protective barrier with enhanced resistance to etching. This preliminary anti-action prepares the hard mask to counteract the harmful etching effects that would otherwise damage the ILD during subsequent processing steps.

Inventive Principle:
Principle #9Preliminary anti-action

Solution Approach 2:

The enhanced hard mask serves as an intermediary protective layer between the etching process and the ILD. By positioning and optimizing this intermediate layer, the patent prevents direct harmful interaction between the etchant and the ILD, thereby protecting the underlying structure during etching operations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ion implantation and annealing process enhances the effectiveness of the hard mask, improving adhesion and reducing etching, resulting in better device performance and reduced damage to the source/drain regions.

Implementation Method 1

performing an ion implantation process to implant dopants into the hard mask, wherein the ion implantation process reduces an etch rate of the hard mask to an oxide etch process

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

performing a thermal anneal process on the hard mask and the first ILD

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS20250374611A1Protective hard mask and methods of making same
Publication Date: 2025.12.04 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250374611A1 patent drawing
  • US20250374611A1 patent drawing
  • US20250374611A1 patent drawing

AI summary

A method includes depositing a first interlayer dielectric (ILD) surrounding a first dummy gate stack and a second dummy gate stack; recessing the first ILD below top surfaces of the first dummy gate stack and the second dummy gate stack; forming a hard mask over the first ILD and between the first dummy gate stack and the second dummy gate stack; performing an ion implantation process to implant dopants into the hard mask, wherein the ion implantation process reduces an etch rate of the hard mask to an oxide etch process; and after performing the ion implantation process, replacing the first dummy gate stack and the second dummy gate stack with a first gate stack and a second gate stack.