Ion-Sequestering Compound for Polymer Viscosity Stability

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Solution Overview

Problem

The use of high viscosity fluids in petroleum and water extraction is limited by ions in water, such as sea water or naturally produced formation water, which degrade viscosifying polymers like guar gum, requiring costly fresh water and limiting the use of certain subterranean formations.

Innovation Solution

A composition including guar gum or its derivatives, Fe2+ or Fe3+ ions, and sodium silicate or sodium metasilicate, with an ion-sequestering compound to sequester ions, maintaining viscosity and hydration properties even in the presence of ions, thereby allowing use with ion-containing water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If ion-containing water (sea water or formation water) is used in drilling fluids with viscosifying polymers, then cost and resource availability improve, but polymer viscosity and hydration properties deteriorate due to ion degradation

Engineering Contradiction:
Improveability to use ion-containing waterVSAvoidpolymer viscosity stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

An ion-sequestering compound is introduced as an intermediary substance that binds to ions in the water, preventing them from interacting with and degrading the viscosifying polymer. This mediator allows the system to use ion-containing water while maintaining polymer stability and viscosity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The ion-sequestering compound converts the harmful effect of ions on polymer stability into a beneficial situation by allowing the use of previously unusable water sources (sea water, formation water) while maintaining or even improving overall system performance through reduced freshwater requirements.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Stability of the object's composition

If fresh water is used to maintain polymer viscosity, then viscosity stability improves, but cost and energy consumption increase

Engineering Contradiction:
Improvepolymer viscosity stabilityVSAvoidenergy for water treatment and transport
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The invention converts the previously harmful ion-containing water into a usable resource by adding ion-sequestering compounds, thereby eliminating the need for costly and energy-intensive freshwater treatment and transport while maintaining polymer viscosity stability.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The ion-sequestering compound provides self-service by automatically binding to ions in the water, preventing them from degrading the polymer without requiring external intervention for water treatment or purification.

Inventive Principle:
Principle #25Self-service

3Stability of the object's composition

If ion-sequestering compounds are added to protect polymer viscosity, then polymer stability improves, but composition complexity increases

Engineering Contradiction:
Improvepolymer viscosity stabilityVSAvoidcomposition formulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The invention changes the chemical parameters of the system by introducing ion-sequestering compounds with specific binding properties, transforming the interaction between ions and polymers from degradative to stable, thereby simplifying the overall system behavior despite the added component.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method and composition effectively maintain viscosity and hydration properties, reducing gel contraction and the need for ion-free water, making it more versatile and cost-effective for downhole applications.

Implementation Method 1

sequestering the ion from the polymer with the ion-sequestering compound

Methodology Applied
Scientific EffectIon sequestration: Adsorption

Data Source

PatentUS9650299B2Methods of using downhole compositions including an ion-sequestering compound
Publication Date: 2017.05.16 HALLIBURTON ENERGY SERVICES INC
  • US9650299B2 patent drawing
  • US9650299B2 patent drawing
  • US9650299B2 patent drawing

AI summary

The present invention relates to methods and compositions for the treatment of subterranean formations. In various embodiments, the method includes obtaining or providing a composition including at least one-ion sequestering compound, sequestering at least one ion from a polymer in the composition with the at least one ion-sequestering compound, and contacting a subterranean material downhole with the composition.