Ion Source Oxidizing Co-Gas Control for Carbon Deposit Removal

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Ion sources in ion implantation systems for molecular carbon implants face efficiency reduction and premature failure due to carbonaceous residue accumulation, which poisons the cathode and causes electrical shorts, limiting the lifetime of the ion source.

Innovation Solution

A system and method that introduces a molecular carbon source gas, such as toluene, and an oxidizing co-gas, like oxygen, into the ion source chamber to ionize and oxidize carbon deposits, forming carbon monoxide and carbon dioxide, which are then removed by a vacuum pump, minimizing residue buildup and extending the ion source's lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If molecular carbon source gas is used for ion implantation, then carbon ions can be generated for doping semiconductor wafers, but carbonaceous residue accumulates on ion source structures causing cathode poisoning and electrical shorts

Engineering Contradiction:
Improvecarbon ion generationVSAvoidion source lifetime
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces oxygen gas as a co-gas that reacts with carbonaceous residue to form carbon monoxide and carbon dioxide, converting the harmful carbon deposits into removable gaseous products. This oxidation process eliminates the residue that would otherwise poison the cathode and cause electrical shorts, thereby extending ion source lifetime while maintaining carbon ion generation capability

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent modifies the gas composition parameters by adding oxygen to the molecular carbon source gas mixture. This parameter change enables chemical reactions that remove carbon residue through oxidation, transforming the operating conditions to prevent harmful accumulation while maintaining the desired ion generation process

Inventive Principle:
Principle #35Parameter changes

2Productivity

If molecular carbon source gas is ionized in the ion source chamber, then carbon ions are produced for the ion beam, but carbon deposits form on chamber surfaces causing source failure

Engineering Contradiction:
Improveion beam productionVSAvoidion source operational lifetime
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The oxygen co-gas converts harmful carbon deposits into beneficial gaseous oxidation products (CO and CO2) that can be pumped away. This process continuously cleans the chamber surfaces during operation, preventing the accumulation that leads to source failure while maintaining continuous ion beam production

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The oxidation process operates continuously during ion source operation, providing ongoing removal of carbon deposits as they form. This continuous cleaning action ensures sustained ion beam production without interruption from residue accumulation or source failure

Inventive Principle:
Principle #20Continuity of useful action

3Quantity of substance

If carbon source gas flows through the ion source chamber, then molecular carbon is available for ionization, but carbonaceous material coats insulators and bridges insulating gaps

Engineering Contradiction:
Improvemolecular carbon availabilityVSAvoidinsulator coating and electrical shorts
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The oxygen co-gas reacts with carbonaceous material that would otherwise coat insulators and bridge gaps, converting it into gaseous CO and CO2. This oxidation prevents the formation of conductive carbon paths on insulating surfaces, eliminating electrical shorts while maintaining carbon source availability

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent employs oxygen as a strong oxidant that rapidly reacts with carbon deposits on insulator surfaces. This accelerated oxidation process effectively prevents carbon coating buildup that would otherwise lead to electrical shorts, maintaining the insulating properties of these components

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach effectively reduces carbon deposits within the ion source chamber, preventing electrical shorts and increasing the ion source's operational lifetime by maintaining its efficiency and performance.

Implementation Method 1

introduces a molecular carbon source gas, such as toluene, and an oxidizing co-gas, like oxygen, into the ion source chamber to ionize and oxidize carbon deposits

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 2

introduces a molecular carbon source gas, such as toluene, and an oxidizing co-gas, like oxygen, into the ion source chamber to ionize and oxidize carbon deposits, forming carbon monoxide and carbon dioxide

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

forming carbon monoxide and carbon dioxide, which are then removed by a vacuum pump

Methodology Applied
Scientific EffectVacuum pumping: Pump

Data Source

PatentUS11756772B2System and method for extending a lifetime of an ion source for molecular carbon implants
Publication Date: 2023.09.12 AXCELIS TECHNOLOGIES INC
  • US11756772B2 patent drawing
  • US11756772B2 patent drawing
  • US11756772B2 patent drawing

AI summary

An ion source assembly and method has a source gas supply to provide a molecular carbon source gas to an ion source chamber. A source gas flow controller controls flow of the molecular carbon source gas to the ion source chamber. An excitation source excites the molecular carbon source gas to form carbon ions and radicals. An extraction electrode extracts the carbon ions from the ion source chamber, forming an ion beam. An oxidizing co-gas supply provides oxidizing co-gas to chamber. An oxidizing co-gas flow controller controls flow of the oxidizing co-gas to the chamber. The oxidizing co-gas decomposes and reacts with carbonaceous residues and atomic carbon forming carbon monoxide and carbon dioxide within the ion source chamber. A vacuum pump system removes the carbon monoxide and carbon dioxide, where deposition of atomic carbon within the ion source chamber is reduced and a lifetime of the ion source is increased.