Ion Source Gas Mixture for Cathode Lifetime Extension

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Solution Overview

Problem

The lifetime of ion sources used in ion implantation processes is shortened due to fluorine-induced oxidation and etching of chamber materials, leading to unstable ion beams and requiring frequent maintenance, which is time-consuming and disruptive to productivity.

Innovation Solution

A gas mixture method involving a carbon-containing dopant gas and a minor gas, such as H2, CF4, Xe, Kr, Ar, PH3, or AsH3, is introduced to dilute the dopant gas and reduce reactive interactions within the ion source chamber, maintaining plasma stability and extending the ion source's operational lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorine-containing gas is used for doping, then doping effectiveness is improved, but cathode lifetime is shortened due to oxidation and etching

Engineering Contradiction:
Improvedoping effectivenessVSAvoidcathode lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces a protective gas layer (argon or nitrogen) as an intermediary between the fluorine-containing dopant gas and the cathode/chamber wall. This protective gas layer acts as a buffer that reduces the direct contact and harmful reactive interactions between fluorine species and the cathode materials, thereby extending cathode lifetime while maintaining doping effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates an inert atmosphere in the ion source chamber by introducing argon or nitrogen gas. This inert environment reduces the oxidation and etching effects of fluorine on the cathode and chamber wall materials, allowing the use of fluorine-containing dopants without severely degrading cathode lifetime.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Productivity

If ion source operates for extended period, then productivity is improved, but ion beam quality degrades

Engineering Contradiction:
Improveoperational continuityVSAvoidion beam quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent enables continuous operation of the ion source by mitigating the degradation mechanisms. The protective gas layer continuously protects the cathode surface during operation, preventing accumulation of harmful effects that would otherwise force intermittent shutdowns for maintenance, thus maintaining both productivity and ion beam quality over extended periods.

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If cathode surface is cleaned frequently, then ion beam stability is improved, but productivity decreases due to maintenance time

Engineering Contradiction:
Improveion beam stabilityVSAvoidmaintenance frequency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent converts the harmful oxidizing effect of fluorine into a beneficial self-cleaning mechanism. By controlling the fluorine exposure, carbon-containing deposits on the cathode surface are oxidized and removed, while the protective gas layer prevents excessive oxidation that would damage the cathode. This reduces the need for frequent manual cleanings and extends operational cycles.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gas mixture effectively mitigates reactive effects, maintaining ion beam quality and extending the mean time between failures (MTBF) of the ion source, reducing the need for frequent maintenance and enhancing productivity.

Implementation Method 1

electrons emitted from the hot cathode collide with gas molecules to generate ions

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 2

electrons emitted from the hot cathode

Methodology Applied
Scientific EffectThermal emission: Thermionic Emission

Implementation Method 3

magnets establish a magnet field to confine those electrons

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 4

fluorine ion has strong oxidation ability and can oxidize metal atoms or other molecules

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 5

positive ions also can possibly accelerate to bombard the cathode to dissociate metal materials of the cathode

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS9147550B2Gas mixture method and apparatus for generating ion beam
Publication Date: 2015.09.29 ADVANCED ION BEAM TECHNOLOGY INC
  • US9147550B2 patent drawing
  • US9147550B2 patent drawing
  • US9147550B2 patent drawing

AI summary

A gas mixture method and apparatus of prolonging lifetime of an ion source for generating an ion beam particularly an ion beam containing carbon is proposed here. By mixing the dopant gas and the minor gas together to generate an ion beam, undesired reaction between the gas species and the ion source can be mitigated and thus lifetime of the ion source can be prolonged. Accordingly, quality of ion beam can be maintained.