Ion Chromatograph Suppressor with Opposing Flow Paths

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Solution Overview

Problem

Current ion chromatographs face challenges in reducing chromatogram background and improving sample analysis accuracy due to limitations in ion suppressor dialysis efficiency.

Innovation Solution

The ion chromatograph design includes a separation column, an ion suppressor with opposing eluent and electrode liquid flow paths, and a detector, where the eluent flow path has opposite flow directions for its portions, and the electrode liquids are supplied to match the eluent flow direction, enhancing electrodialysis efficiency and reducing chromatogram background.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional ion suppressor design with single flow path is used, then device complexity is low, but chromatogram background cannot be reduced sufficiently

Engineering Contradiction:
Improvechromatogram background reductionVSAvoidion suppressor structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The ion suppressor is divided into multiple flow-path portions (first, second, third, and fourth portions) with opposite flow directions. This segmentation allows different regions of the suppressor to perform electrodialysis with optimized flow patterns, improving background reduction capability while maintaining manageable device complexity through modular design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention introduces a multi-dimensional flow path configuration where eluent and electrode liquid flow in opposite directions through different portions of the suppressor. This spatial arrangement creates multiple interaction zones for electrodialysis, enhancing the suppression effect and reducing chromatogram background beyond what single-direction flow can achieve.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Measurement precision

If electrodialysis efficiency is improved by optimizing flow paths, then chromatogram background is reduced, but uniformity of electrodialysis efficiency across flow path becomes challenging

Engineering Contradiction:
Improveelectrodialysis efficiency uniformityVSAvoidflow path configuration
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

Different flow-path portions are designed with opposite flow directions to create locally optimized electrodialysis conditions. The first and second portions have one flow direction pattern while the third and fourth portions have the opposite pattern, ensuring that each local region contributes uniformly to overall electrodialysis efficiency and background reduction.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The flow path configuration creates a periodic alternation of flow directions through the suppressor. By alternating the flow direction patterns in successive portions, the system maintains uniform electrodialysis efficiency across the entire suppressor length, preventing localized inefficiencies that would occur with single-direction flow.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the accuracy of sample analysis by uniformly enhancing electrodialysis efficiency across the eluent flow path, reducing chromatogram background and maintaining high analysis precision.

Implementation Method 1

Ion exchange is performed by electrodialysis between an eluent in the eluent flow path, and the first regeneration liquid flow path and the second regeneration liquid flow path, whereby electrical conductivity of the eluent is lowered

Methodology Applied
Scientific EffectElectrodialysis: Ion Exchange

Implementation Method 2

A sample is separated into ion species components by passing through the separation column

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Data Source

PatentUS11982653B2Ion chromatograph and ion component analysis method
Publication Date: 2024.05.14 SHIMADZU CORP
  • US11982653B2 patent drawing
  • US11982653B2 patent drawing
  • US11982653B2 patent drawing

AI summary

First and second flow-path portions are opposite to each other, and communicate with each other such that a direction in which an eluent flows through the first flow-path portion and a direction in which an eluent flows through the second flow-path portion are opposite to each other. First and second electrode liquid flow paths are respectively opposite to the first and second flow-path portions. First and second electrode liquids are respectively supplied to the first and second electrode liquid flow paths, such that a direction in which the first electrode liquid flows through the first electrode liquid flow path is same as a direction in which an eluent flows through the first flow-path portion and a direction in which the second electrode liquid flows through the second electrode liquid flow path is same as a direction in which an eluent flows through the second flow-path portion.