2D Ion Trap Multi-Polarity Trapping via Dynamic Axial Fields

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Solution Overview

Problem

Current 2D ion traps cannot simultaneously trap positive and negative ions due to the repulsive DC field's attractive nature for ions of opposite polarity, preventing simultaneous trapping and reaction in the same region.

Innovation Solution

A method involving an ion guide with RF voltage potential for radial confinement and DC voltage barriers of the same polarity as each ion group, along with axial fields to push ions toward trapping barriers, allowing for separate trapping regions or alternating axial field directions to trap ions of opposite polarities effectively.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a DC field is applied at the entrance and exit of a 2D ion trap to prevent ions from leaving along the axis, then ions of one polarity are effectively trapped, but ions of the opposite polarity are attracted by the repulsive field and lost from the trap

Engineering Contradiction:
Improvetrapping effectivenessVSAvoidpolarity selectivity
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies dynamic axial fields that alternate in direction at a frequency matching the ion oscillation frequency. This dynamic approach allows the field to repel ions of one polarity during part of the cycle while attracting ions of the opposite polarity during another part, effectively trapping both polarities simultaneously. The field transitions from static to dynamic to resolve the polarity selectivity issue.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent employs periodic axial fields that oscillate at the ion oscillation frequency to trap ions of both polarities. The periodic reversal of the field direction ensures that ions of either polarity experience a net repulsive force over each cycle, preventing them from escaping while maintaining trapping effectiveness for both polarities.

Inventive Principle:
Principle #19Periodic action

2Adaptability or versatility

If a 3D ion trap is used to trap ions of both polarities simultaneously, then reactions between positive and negative ions can occur, but the trapping volume is limited compared to 2D ion traps

Engineering Contradiction:
Improvemulti-polarity trapping capabilityVSAvoidtrapping volume
Core Design Contradiction:
Adaptability or versatilityVSVolume of stationary object

Solution Approach 1:

The patent combines the axial confinement capability of 2D traps with dynamic field control to achieve 3D-like trapping of both polarities. By using dynamic axial fields in addition to radial RF confinement, the system effectively creates a three-dimensional trapping region that maintains the large volume advantage of 2D traps while enabling multi-polarity trapping.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Device complexity

If only one polarity of ions is trapped and analyzed at a time in a 2D ion trap, then the trapping and analysis are simple, but reactions between positive and negative ions cannot occur

Engineering Contradiction:
Improvetrapping control simplicityVSAvoidion reaction capability
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent uses dynamic axial fields that can be controlled in amplitude and frequency to manage the trapping of different ion polarities. By adjusting the field parameters, the system can trap both polarities simultaneously or sequentially, enabling ion reactions while maintaining relatively simple control mechanisms.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the simultaneous trapping and analysis of both positive and negative ions in a 2D ion trap, facilitating reactions and partial charge neutralization, similar to 3D ion traps, while maintaining a larger trapping volume.

Implementation Method 1

applying an RF voltage potential to the first ion guide for confining the first group of ions and the second group of ions radially within the first ion guide

Methodology Applied
Scientific EffectRF voltage potential: Electromagnetic Induction

Implementation Method 2

providing a trapping barrier to the second end of the first ion guide for trapping the first group of ions within the first ion guide, wherein the trapping barrier is a DC voltage barrier of the same polarity as the first group of ions

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 3

providing an axial field for pushing the first group of ions toward the trapping barrier and for pushing the second group of ions toward the first end

Methodology Applied
Scientific EffectAxial electric field: Electric Field

Data Source

PatentUS7759637B2Method for storing and reacting ions in a mass spectrometer
Publication Date: 2010.07.20 DH TECH DEVMENT PTE
  • US7759637B2 patent drawing
  • US7759637B2 patent drawing
  • US7759637B2 patent drawing

AI summary

A method of analyzing ions is provided having a first ion guide with first and second ends and introducing a first group of ions and a second group of ions of opposite polarity into the first ion guide, and applying an RF voltage potential to the first ion guide for confining the first and second groups of ions radially within the first ion guide. A first trapping barrier is provided to the first end of the first ion guide for trapping the first group of ions within the first ion guide and a second trapping barrier is provided to the second end of the first ion guide for trapping the second group of ions within the first ion guide and an axial field is provided for pushing the first group of ions toward the first trapping barrier and pushing the second group of ions toward the second trapping barrier.