Ionic Liquid Processed Artificial Timber

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Solution Overview

Problem

Current methods for producing artificial timber using ionic liquids result in low-value products like sound-absorbing boards due to limitations in constructing a high-performance, porous structure with enhanced particle components, and existing processes require high energy and complex manufacturing conditions.

Innovation Solution

An environment-friendly ionic liquid processing system is developed, optimizing the component ratio and solvent replacement system to create a nanofiber crosslinking microparticle-structured porous artificial timber, which avoids high temperature and pressure conditions and uses a solvent replacement process with acetone-alcohol solutions to achieve a uniform fiber network.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If ionic liquid is used to dissolve timber components, then solubility and uniform coagulation are improved, but only low-value aerogel products can be prepared with limited applications

Engineering Contradiction:
Improvesolubility of cellulose and ligninVSAvoidapplication value of resulting product
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent applies porous materials principle by constructing a hierarchical porous structure with microparticles (1-10 μm) containing nanofibers (10-100 nm) as fillers. This porous architecture transforms the dissolved timber components into a high-value artificial timber with enhanced specific area (5-50 m²/g) and improved mechanical properties, moving beyond low-value aerogel products to applications in construction and structural materials.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent employs composite materials principle by creating a multi-component system where microparticles and nanofibers are combined in a porous matrix. The composite structure integrates cellulose, hemicellulose, and lignin in specific ratios (cellulose: 30-70 wt%, hemicellulose: 10-40 wt%, lignin: 5-20 wt%) to achieve both solubility in ionic liquid and high mechanical strength, resolving the contradiction between dissolution capability and product value.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If traditional adhesive and high temperature thermo-pressing process are used, then artificial boards can be manufactured, but environmental pollution and high energy consumption occur

Engineering Contradiction:
Improvemanufacturability of artificial boardsVSAvoidenvironmental pollution and energy consumption
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent applies extraction principle by removing harmful adhesive substances and high-temperature processing steps from the manufacturing process. Instead, it uses ionic liquid dissolution followed by controlled coagulation to form the artificial timber structure, eliminating environmental pollution and reducing energy consumption while maintaining ease of manufacture through a simplified process flow.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs parameter changes principle by transitioning from high-temperature thermo-pressing conditions to room temperature or mild temperature processing. The ionic liquid enables dissolution and shaping at low temperatures, and the subsequent coagulation process occurs under ambient conditions, dramatically reducing energy consumption and eliminating the need for adhesive chemicals.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If solvent replacement process is used to remove ionic liquid, then uniform fiber network is achieved, but construction of multi-pore passage structure with enhanced particles is limited

Engineering Contradiction:
Improveuniformity of fiber networkVSAvoidmulti-pore passage structure
Core Design Contradiction:
Stability of the object's compositionVSShape

Solution Approach 1:

The patent applies segmentation principle by dividing the fiber network into hierarchical levels: nanofibers (10-100 nm) segmented within microparticles (1-10 μm), which are further distributed in a porous matrix. This segmented structure creates multi-pore passages at different scales while maintaining uniform fiber distribution through the solvent replacement process, resolving the contradiction between network uniformity and structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs dimensionality change principle by creating a three-dimensional hierarchical porous structure from the two-dimensional uniform fiber network. The solvent replacement process preserves fiber uniformity while the controlled phase separation and drying procedures generate multi-pore passages extending in three dimensions, with pore sizes ranging from nanometer to micrometer scales, adding structural dimensionality without compromising compositional uniformity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting artificial timber exhibits higher specific area, compression resistance, lower density, and reduced water absorption, maintaining integrity under deformation and boiling conditions, offering improved mechanical properties and reduced material costs.

Implementation Method 1

Ionic liquid is an environment-friendly room temperature solvent, has better solubility for the cellulose and the lignin, and can dissolve them into a nanometer or even molecular level

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

Usually, acetone-alcohol mixed solutions of different concentrations can be used for replacement and dissolving to finally obtain the timber products having a uniform fiber network

Methodology Applied
Scientific EffectSolvent replacement: Liquid-Liquid Extraction

Implementation Method 3

An artificial timber is formed by extracting lignin from natural timber and winding around fibers utilizing the viscidity of the lignin to coagulate the fibers together

Methodology Applied
Scientific EffectCoagulation: Coagulation

Data Source

PatentUS11466141B2Artificial timber
Publication Date: 2022.10.11 ZHEJIANG FORESTRY UNIVERSITY
  • US11466141B2 patent drawing
  • US11466141B2 patent drawing
  • US11466141B2 patent drawing

AI summary

An artificial timber comprises the following components in parts by weight: 35-50 parts of cellulose, 20-35 parts of hemicellulose and 15-35 parts of lignin, wherein the artificial timber has a density of 0.01-0.05 g/cm3. The preparing method comprises: (1) dissolving 15-35 parts by weight of lignin, 35-50 parts by weight of cellulose and 20-35 parts by weight of hemicellulose with an ionic liquid; (2) cleaning and replacing it with water to obtain a lignocellulose hydrogel; and (3) drying the lignocellulose hydrogel to obtain an artificial timber. The artificial timber prepared by the present invention is large in specific area, low in density, low in material energy consumption, moderate in condition and easy for operation. The artificial timber obtained by the present invention is regular in shape and is shaped like a sandy beige cylinder without obvious damage and deformation, which indicates that such artificial timber with high specific area has well molding capacity.