Ionic Liquid Desiccant Heat Pump for Non-Corrosive Dehumidification

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Solution Overview

Problem

Conventional liquid desiccants used for moisture removal are corrosive and toxic, leading to environmental and operational challenges, and they precipitate at high concentrations and low relative humidity, making them inefficient and costly to maintain.

Innovation Solution

The use of ionic liquid desiccants, which are non-corrosive and non-toxic, designed to optimize desorption temperature and performance, integrated with electrochemical heat exchangers to improve the coefficient of performance by 25-40% and create a more efficient cooling system that dehumidifies air without over-cooling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional liquid desiccants (lithium chloride, calcium chloride) are used for moisture removal, then moisture absorption capacity is improved, but corrosiveness and toxicity increase, and environmental impact worsens

Engineering Contradiction:
Improvemoisture absorption capacityVSAvoidcorrosiveness and toxicity
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the desiccant from conventional inorganic salts (lithium chloride, calcium chloride) to ionic liquids with specific molecular structures. This parameter change maintains high moisture absorption capacity while eliminating corrosiveness and toxicity, directly resolving the technical contradiction between absorption performance and environmental safety

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite ionic liquid formulations combining different cations and anions to optimize both moisture absorption capacity and environmental compatibility. These composite materials achieve the dual benefit of high performance and low harm, resolving the contradiction between quantity of substance and harmful factors

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional liquid desiccants are used at high concentrations, then moisture absorption performance is improved, but precipitation of solid salts occurs at low relative humidity, reducing efficiency

Engineering Contradiction:
Improvemoisture absorption performanceVSAvoidprecipitation resistance
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the physical-chemical parameters of the desiccant system by using ionic liquids instead of inorganic salt solutions. This parameter change allows the system to maintain high concentration without precipitation, as ionic liquids remain in liquid phase across a wider concentration and humidity range, resolving the contradiction between absorption performance and composition stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent exploits the phase transition properties of ionic liquids, which remain in the liquid phase at conditions where conventional salt solutions would precipitate. This prevents solid formation and maintains system efficiency across varying humidity levels, resolving the contradiction between performance and stability

Inventive Principle:
Principle #36Phase transitions

3Quantity of substance

If conventional HVAC systems cool air below dew point for dehumidification, then moisture removal is achieved, but energy efficiency decreases due to over-cooling and reheating requirements

Engineering Contradiction:
Improvemoisture removal effectivenessVSAvoidenergy efficiency
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The patent replaces the mechanical cooling-based dehumidification system with a chemical absorption system using ionic liquid desiccants. This substitution eliminates the need for over-cooling and subsequent reheating, achieving effective moisture removal while significantly improving energy efficiency by avoiding the thermodynamic inefficiencies of conventional HVAC cycles

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental operating parameter of dehumidification from temperature-based (cooling below dew point) to concentration-based (chemical absorption). This parameter change allows moisture removal at ambient temperatures without the energy-wasting cycle of over-cooling and reheating, resolving the contradiction between moisture removal effectiveness and energy efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ionic liquid desiccants provide a safer, less expensive, and more efficient method for removing moisture from gas sources, maintaining performance across a wide range of temperatures and humidity levels, reducing environmental impact and operational costs.

Implementation Method 1

contact a gas source containing a high percentage of H2O with an absorbent comprising said liquid desiccant, to absorb at least a portion of the H2O vapor from the H2O vapor-containing gas source

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

an ionic liquid desiccant to remove moisture from the system

Methodology Applied
Scientific EffectDesorption: Desorption

Data Source

PatentUS10386084B2Heat pumps utilizing ionic liquid desiccant
Publication Date: 2019.08.20 USA FORTESCUE IP INC
  • US10386084B2 patent drawing
  • US10386084B2 patent drawing
  • US10386084B2 patent drawing

AI summary

An ionic liquid desiccant system utilizes an ionic liquid desiccant to draw moisture from a working fluid, such as air that flow into an enclosure, such as a home. The desiccant may be mixed with the working fluid or a separator that allows moisture transport therethrough may be configured between the ionic liquid desiccant and the working fluid. The ionic liquid desiccant system may be part of an air conditioning system and may remove the moisture from air that is cooled by flowing over an evaporator or heat exchanger coupled with the evaporator. The ionic liquid desiccant may be pumped from a desiccant chamber to a regenerator chamber to remove absorbed moisture. A dual-purpose chamber may act as a desiccant chamber and as a regenerator chamber. A refrigeration system may have an electrochemical compressor and may utilize metal hydride heat exchangers.