Ionic Liquid Fiber Welding to Preserve Native Biopolymer Structure

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Solution Overview

Problem

Current methods for producing natural fiber composites, such as those using synthetic polymers and ionic liquids, face limitations in scalability and efficiency, particularly in maintaining the native structure and properties of biopolymers like cellulose and silk, and struggle with handling viscous solutions at elevated temperatures.

Innovation Solution

The development of a fiber welding process using ionic liquids to fuse natural fibers without full dissolution, allowing for control over the engineering of final products by manipulating fiber bundles before welding, and incorporating functional materials within the fiber matrix, with a solvent recovery system for efficient solvent recycling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If natural fibers are fully dissolved in ionic liquid solutions to create biopolymer composites, then the material can be easily processed and molded, but the original fiber structure and native material properties are disrupted and lost

Engineering Contradiction:
ImproveprocessabilityVSAvoidfiber structure integrity
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent applies partial dissolution by controlling the ionic liquid treatment to only partially dissolve the natural fiber biopolymers rather than complete dissolution. This allows the fiber structure to be partially modified for improved processability while retaining enough native structure to maintain material properties, directly resolving the contradiction between ease of manufacture and composition stability

Inventive Principle:
Principle #16Partial or excessive action

2Quantity of substance

If high concentrations of biopolymer are dissolved in ionic liquid solutions (e.g., 10% cotton with 90% ionic liquid), then more polymer can be processed, but the solutions become viscous and difficult to handle even at elevated temperatures

Engineering Contradiction:
Improvepolymer concentrationVSAvoidsolution handling
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent changes physical parameters including temperature and ionic liquid composition to manage solution viscosity. By elevating temperature and selecting specific ionic liquids with appropriate properties, the system can process higher polymer concentrations while maintaining acceptable handling characteristics, resolving the contradiction between quantity of substance and ease of operation

Inventive Principle:
Principle #35Parameter changes

3Shape

If traditional solution-based methods are used to process biopolymers, then the material can be molded into desired shapes, but there is a physical limit to how much polymer can be dissolved and control over engineering is reduced

Engineering Contradiction:
Improveproduct geometryVSAvoidengineering control
Core Design Contradiction:
ShapeVSAdaptability or versatility

Solution Approach 1:

The patent applies preliminary action by manipulating and shaping the fiber bundles into desired configurations before the welding process occurs. This allows engineers to control the final product geometry and structure through pre-arrangement of fibers, providing adaptability and versatility that overcomes the limitations of traditional solution-based molding methods

Inventive Principle:
Principle #10Preliminary action

4Ease of manufacture

If synthetic polymers are used for welding natural fibers, then the welding process is simple and effective, but petroleum-based materials are required which reduces sustainability

Engineering Contradiction:
Improvewelding simplicityVSAvoidpetroleum dependency
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent applies self-service by using ionic liquids that can dissolve and weld natural fiber biopolymers without requiring synthetic polymer additives. The ionic liquid system itself provides the welding function through controlled dissolution and reformation of natural fiber bonds, eliminating petroleum-based materials while maintaining welding effectiveness and simplicity

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enables the production of robust, scalable composite materials with enhanced physical and chemical properties, such as increased tensile strength and hydrophobicity, while reducing the need for petroleum-based materials and improving handling and processing efficiency.

Implementation Method 1

Ionic liquids (e.g., 1-ethyl-3-methylimidazolium acetate) can dissolve natural fiber biopolymers (e.g., cellulose and silk) without derivatization

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

a process solvent application zone 2, configured for applying a process solvent to a substrate

Methodology Applied
Scientific EffectLiquid-phase mass transfer: Diffusion

Data Source

PatentUS11766835B2Methods, processes, and apparatuses for producing welded substrates
Publication Date: 2023.09.26 NATURAL FIBER WELDING INC
  • US11766835B2 patent drawing
  • US11766835B2 patent drawing
  • US11766835B2 patent drawing

AI summary

A welding process may be configured to convert a substrate into a welded substrate by applying a process solvent to the substrate, wherein the process solvent interrupts one or more intermolecular force between one or more component in the substrate. The substrate may be configured as a natural fiber, such as cellulose, hemicelluloses, and silk. The process solvent may be configured as an ionic-liquid based solvent and the welded substrate may be a congealed network after the process solvent has been adequately swollen and/or mobilized the substrate. A welding process may be configured such that individual fibers of a substrate are not fully dissolved such that material in the fiber core may be left in the native state by controlling process variables. The welding process fibers may have a tenacity 10% or 20% greater or a diameter 25% less than that of a cellulosic-based yarn substrate.