Selective Metal Deposition on Patterned Substrates Using Ionic Liquid

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing techniques for embedding metal layers in insulating films face challenges in selectively positioning the metal layer below the insulating film surface, leading to inefficiencies and potential particle generation.

Innovation Solution

A substrate processing method involving the use of an ionic liquid with a metal salt, followed by energy application to precipitate a metal layer on a conductor surface through a reduction reaction, utilizing heating or microwave irradiation to selectively form the metal pattern conforming to conductor patterns while suppressing precipitation on insulator surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional metal layer embedding techniques are used to position metal layers below insulating film surfaces, then metal layer positioning is achieved, but particle generation occurs and processing efficiency decreases

Engineering Contradiction:
Improvemetal layer positioning precisionVSAvoidparticle generation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical parameters of the deposition process by using ionic liquids with specific metal salts and controlling reduction reactions through energy application. This allows selective metal precipitation on conductor surfaces while avoiding particle generation associated with conventional embedding techniques

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces mechanical embedding processes with a chemical deposition process using ionic liquids. The metal layers are formed in-situ through reduction reactions on conductor surfaces, eliminating the need for mechanical trench filling and subsequent planarization that cause particle generation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If conventional metal layer embedding is performed, then metal layers can be formed, but selective deposition on conductors while suppressing insulator precipitation is difficult to achieve

Engineering Contradiction:
Improveselective deposition precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention applies local quality by making the ionic liquid composition and energy application parameters specific to conductor surfaces. The reduction reaction is selectively triggered on conductors through their electrical properties, while insulators remain unaffected, achieving high selective deposition precision

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The conductor surfaces automatically catalyze the reduction reaction of metal salts in the ionic liquid through their electrical conductivity. The conductors serve their dual function as both structural elements and reaction catalysts, simplifying the overall process while maintaining high selectivity

Inventive Principle:
Principle #25Self-service

3Manufacturing precision

If energy is applied to precipitate metal from ionic liquid, then metal layer formation is achieved, but energy consumption increases

Engineering Contradiction:
Improvemetal pattern formation precisionVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The invention optimizes energy parameters by using moderate heating temperatures and controlled microwave irradiation. The energy is applied selectively and locally to regions containing conductors, minimizing overall energy consumption while maintaining high metal pattern formation precision

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces high-energy mechanical sputtering or evaporation processes with low-energy chemical reduction reactions. The metal deposition occurs through spontaneous reduction of metal salts on conductor surfaces, requiring minimal external energy input compared to physical vapor deposition methods

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables precise formation of metal patterns on conductors, reducing particle generation and enhancing selective deposition, thereby improving processing efficiency and precision.

Implementation Method 1

applying energy to the substrate includes forming a metal layer on a surface of the conductor by precipitating a metal of the metal salt on the surface of the conductor by a reduction reaction of the metal salt

Methodology Applied
Scientific EffectReduction reaction: Reduction

Implementation Method 2

utilizing heating or microwave irradiation to selectively form the metal pattern

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

utilizing heating or microwave irradiation to selectively form the metal pattern conforming to conductor patterns

Methodology Applied
Scientific EffectMicrowave irradiation: Microwave Radiation

Data Source

PatentUS20250347002A1Substrate processing method and substrate processing system
Publication Date: 2025.11.13 TOKYO ELECTRON LTD
  • US20250347002A1 patent drawing
  • US20250347002A1 patent drawing
  • US20250347002A1 patent drawing

AI summary

A substrate processing method includes: preparing a substrate in which patterns of a conductor and an insulator are formed in a substrate surface of the substrate; coating the substrate surface of the substrate with an ionic liquid including a metal salt; and applying energy to the substrate coated with the ionic liquid. The applying the energy to the substrate includes forming a metal layer on a surface of the conductor by precipitating a metal of the metal salt on the surface of the conductor by a reduction reaction of the metal salt.