Ionic Liquid Lubricant Additives for Solubility and Wear Reduction

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Solution Overview

Problem

Existing lubricant compositions face challenges with ionic liquids that have limited solubility and stability in certain lubricant base oils, leading to reduced anti-friction and anti-wear properties.

Innovation Solution

Incorporation of novel ionic liquid salts with binuclear molybdenum-containing metallate anions, such as [Mo2A3Cd]2-, into lubricating oil and grease compositions to enhance solubility and stability while maintaining or improving anti-wear and friction reduction properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing ionic liquids are used as friction reduction and anti-wear additives, then anti-friction and anti-wear properties are provided, but solubility and stability in certain lubricant base oils are limited

Engineering Contradiction:
Improveanti-friction and anti-wear propertiesVSAvoidsolubility and stability in lubricant base oils
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the ionic liquid by introducing binuclear molybdenum-containing metallate anions with specific formulas [Mo2A3Cd]2- where A and C are O or S. This structural modification with binuclear molybdenum cores and variable oxygen/sulfur content optimizes both solubility in lubricant base oils and stability while maintaining anti-wear and friction reduction properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite ionic liquid structures combining organic cations with binuclear molybdenum metallate anions. This composite approach integrates the lubricity-providing molybdenum core with organic components that enhance solubility and stability in various lubricant base oils, achieving multiple properties simultaneously

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If ionic liquid salts with binuclear molybdenum-containing metallate anions are incorporated into lubricant compositions, then solubility and stability are improved, but the complexity of the additive structure increases

Engineering Contradiction:
Improvesolubility and stability in lubricant base oilsVSAvoidcomplexity of ionic liquid salt structure
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent systematically varies parameters within the binuclear molybdenum metallate anion structure, specifically the oxidation state of molybdenum and the ratio of oxygen to sulfur atoms. This controlled parameter variation allows optimization of solubility and stability while managing structural complexity through defined chemical formulas [Mo2A3Cd]2-

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel ionic liquid salts provide improved solubility and stability, resulting in enhanced anti-wear and friction reduction performance compared to existing ionic liquids, ensuring effective lubrication in various applications.

Implementation Method 1

Friction reduction additives are generally included in lubricating oil compositions to reduce the friction between moving parts of the system. An example of commercially available friction reduction additive is the compound known as molybdenum dithiocarbamate MoDTC

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

Lubricant compositions generally comprise a base oil of lubricating viscosity together with one or more additives to deliver properties such as reduced friction and wear

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentEP4347753B1Friction and wear reduction additives
Publication Date: 2025.11.19 PETROLIAM NASIONAL BHD
  • EP4347753B1 patent drawingFigure 1~2
  • EP4347753B1 patent drawingFigure 3~4
  • EP4347753B1 patent drawingFigure 5~6

AI summary

The present invention relates to additives for reducing friction and wear in lubricant compositions such as lubricating oils and greases. In particular, the present invention relates to novel salts and their use in lubricating oil compositions and grease compositions for reducing friction and wear.