Ionic Polymer Hair Care Systems for Frizz Control and Damage Reduction

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Solution Overview

Problem

Current hair care products struggle to effectively address hair damage caused by physical manipulation, environmental factors, and chemical treatments, leading to issues like frizz, breakage, and loss of moisture, while also seeking to maintain a balance between cleansing and conditioning without causing further damage.

Innovation Solution

The use of hair care systems that combine surfactant-containing compositions with ionic polymers functionalized with carboxylic acid moieties, alkoxysilanes, and nonionic latex polymers to provide improved frizz control, manageability, and conditioning benefits, including detangling and styling ease, through booster compositions and hair treatment products like shampoos, conditioners, and masks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If anionic surfactants are used in shampoos to produce good foams and effectively cleanse the hair, then cleansing performance is improved, but the hair becomes more damaged, tangled, dry, and less soft/smooth

Engineering Contradiction:
Improvecleansing performanceVSAvoidhair damage and tangling
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces ionic polymers as intermediary substances that mediate between the cleansing action of anionic surfactants and the hair. These polymers form protective complexes with the surfactants, reducing their direct damaging contact with hair while maintaining cleansing efficacy. The ionic polymers act as a buffer layer that prevents excessive stripping of natural oils and reduces static electricity that causes tangling.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates composite surfactant systems combining anionic surfactants with ionic polymers in specific ratios. This composite approach allows the mixture to exhibit both effective cleansing properties from the anionic surfactant and protective conditioning properties from the ionic polymer, resolving the contradiction between cleansing power and hair integrity.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If cationic surfactants are added into conditioners to enhance conditioning properties, then hair softness and detangling are improved, but the conditioners are easily washed off from the hair, especially upon consecutive shampooing

Engineering Contradiction:
Improveconditioning propertiesVSAvoidconditioner retention
Core Design Contradiction:
Ease of operationVSDuration of action of stationary object

Solution Approach 1:

The patent modifies the chemical parameters of conditioning agents by using ionic polymers with specific charge densities and molecular weights. These parameter adjustments allow the conditioner to bind more strongly to hair through multiple interaction mechanisms (electrostatic, hydrophobic, and hydrogen bonding), significantly improving retention against washing while maintaining conditioning efficacy.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The ionic polymers concentrate conditioning benefits at the hair surface through localized complex formation. The polymers have affinity for both the hair cuticle and the cationic surfactants, creating localized zones of enhanced conditioning that are more resistant to rinsing while still providing softness and detangling benefits.

Inventive Principle:
Principle #3Local quality

3Shape

If silicones are included into conditioners to provide smoothing benefits and wash resistance, then hair smoothness and conditioner retention are improved, but the hair is weighed down too much and becomes more difficult to style

Engineering Contradiction:
Improvehair smoothnessVSAvoidstyling ease
Core Design Contradiction:
ShapeVSEase of operation

Solution Approach 1:

The patent replaces traditional silicone compounds with ionic polymers that have tunable molecular weight, charge density, and hydrophilicity parameters. By adjusting these parameters, the invention achieves similar smoothing and retention effects without the excessive weight and stiffness associated with silicones, thereby maintaining styling flexibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The ionic polymers provide a more homogeneous distribution of conditioning benefits throughout the hair structure compared to silicones. They penetrate and bind uniformly along the hair shaft, providing consistent smoothness without creating the heavy, uniform coating that silicones apply, which restricts hair movement and styling.

Inventive Principle:
Principle #33Homogeneity

4Quantity of substance

If hard water is used for hair washing, then mineral deposits accumulate on the hair over time, but this prevents moisture intake into the hair, making it dry, frizzy, and prone to tangles

Engineering Contradiction:
Improvemineral deposit accumulationVSAvoidmoisture loss and frizz
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The ionic polymers act as intermediaries between hard water minerals and the hair. They bind to mineral ions (calcium, magnesium) in the water, preventing these minerals from directly depositing on and blocking the hair cuticle. This intermediary binding maintains cuticle porosity and allows continued moisture absorption while still utilizing hard water for washing.

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentUS11642301B2Systems, kits, and methods for treating hair with compositions containing ionic polymers
Publication Date: 2023.05.09 LOREAL SA
  • US11642301B2 patent drawing
  • US11642301B2 patent drawing
  • US11642301B2 patent drawing

AI summary

The present disclosure relates to hair care systems comprising: (1) a booster composition containing at least one ionic polymer functionalized with at least one carboxylic acid moiety; optionally, at least one compound selected from an alkoxysilane, a nonionic latex polymer, or mixtures thereof; a thickening agent; and a cosmetically acceptable carrier; and (2) a hair treatment composition containing at least one surfactant selected from an anionic surfactant, an amphoteric surfactant, a cationic surfactant, a nonionic surfactant, or mixtures thereof. The hair care systems of the present disclosure can be used to clean and/or condition hair, as well impart frizz control and manageability benefits to hair.