Phase-Change Ionic Redox Transistor for Stable Analog Memory

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Solution Overview

Problem

Conventional digital computing devices are inefficient in executing artificial neural networks (ANNs) due to the unpredictability and high energy consumption of existing analog memory devices like RRAM and PCM, which suffer from information loss at micro- and nano-scales due to charge leakage.

Innovation Solution

A thermally sensitive ionic redox transistor with a variable-conductance channel, an electrolyte layer, and a reservoir layer, where the electrolyte layer undergoes a state change at a specific temperature, allowing for controlled ion migration and stable conductance state retention, enabling efficient programming and retention of analog states for extended periods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of information

If RRAM or PCM devices are used for analog memory, then analog state programming is achieved, but information loss occurs due to charge leakage and nonuniform heating

Engineering Contradiction:
Improveinformation lossVSAvoidprogramming predictability
Core Design Contradiction:
Loss of informationVSReliability

Solution Approach 1:

The patent replaces conventional electronic switching mechanisms with a thermally activated ionic transport mechanism. The electrolyte layer undergoes a phase transition from solid to liquid state at a specific temperature, enabling ion migration between the channel and reservoir layers. This thermal-ionic mechanism substitutes the electronic charge-based mechanism, eliminating charge leakage issues and achieving non-volatile memory retention while maintaining programming predictability through controlled phase transition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes a phase transition in the electrolyte layer material (from solid to liquid state) at a specific temperature to control ion transport. Below the transition temperature, the solid electrolyte prevents ion migration and retains the programmed state. Above the transition temperature, the liquid electrolyte enables ion migration for programming. This phase transition mechanism provides a reliable, predictable switching behavior that resolves the contradiction between information retention and programming control.

Inventive Principle:
Principle #36Phase transitions

2Length of moving object

If micro- and nano-scale devices are used, then device miniaturization is achieved, but charge leakage through electronic switches causes information loss

Engineering Contradiction:
Improvedevice sizeVSAvoidinformation loss
Core Design Contradiction:
Length of moving objectVSLoss of information

Solution Approach 1:

The patent replaces the electronic switch-based control mechanism with a thermal-ionic control mechanism. Instead of using electronic switches that suffer from charge leakage at micro- and nano-scales, the invention uses temperature-controlled phase transition of the electrolyte to enable or disable ion transport. This substitution eliminates the charge leakage problem inherent in electronic switches while maintaining effective device control at scaled dimensions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the control parameter from electrical voltage (prone to leakage at small scales) to thermal temperature. By controlling the temperature relative to the electrolyte's phase transition point, the device achieves reliable on/off control of ion transport without the charge leakage issues that plague electronic switches at micro- and nano-scales. This parameter change enables information retention in miniaturized devices.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional digital computing devices are used for ANN execution, then existing hardware is utilized, but computational efficiency is poor

Engineering Contradiction:
Improvecomputational efficiencyVSAvoidhardware architecture
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the operational mechanism of the memory device from electronic charge-based operation to thermal-ionic operation. The electrolyte's phase transition at a specific temperature enables controlled ion migration, creating analog conductance states that can be used for neuromorphic computing. This parameter change allows the device to function as an analog memory element suitable for efficient ANN execution, bridging the gap between conventional hardware and neuromorphic computing requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The thermally sensitive ionic redox transistor provides predictable and energy-efficient programming and retention of conductance states, reducing information loss and improving scalability for neuromorphic computing applications.

Implementation Method 1

the electrolyte layer undergoes a state change at a state transition temperature or within a state transition temperature range

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

the ionic compound can be solid below the state transition temperature but liquid above the state transition temperature

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

the electrolyte layer comprises a solid acid that undergoes a state transition at a state transition temperature

Methodology Applied
Scientific EffectState transition: Phase Change

Implementation Method 4

the electrolyte layer comprises a solid-state cation conductor that undergoes a state change at a state transition temperature

Methodology Applied
Scientific EffectState change: Phase Change

Data Source

PatentUS11942282B1Thermally sensitive state change ionic redox transistor
Publication Date: 2024.03.26 NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA LLC
  • US11942282B1 patent drawing
  • US11942282B1 patent drawing
  • US11942282B1 patent drawing

AI summary

A thermally sensitive ionic redox transistor comprises a channel, a reservoir layer, and an electrolyte layer disposed between the channel and the reservoir layer. A conductance of the channel is varied by changing concentration of ions in the channel layer. The electrolyte layer is configured to undergo a state change at a state transition temperature. Below the state transition temperature, ions in the electrolyte layer are substantially immobile. Above the state transition temperature, ions can move freely between the reservoir layer and the channel across the electrolyte layer in response to a voltage being applied between the channel and the reservoir layer. When the device is cooled below the state transition temperature or temperature range, the ions are trapped in one or more of the layers because the electrolyte layer loses its ionic conductivity. A state of the redox transistor can be read by measuring the conductance of the channel.