Tunable Ionic Electronic Transistor Solid Electrolyte Integration

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Solution Overview

Problem

Resistive memory devices, such as memristors, face issues with read noise, write noise, and write non-linearity, and three-terminal devices with ionic liquid gates have integration challenges with solid-state devices and slow switching speeds.

Innovation Solution

An ionic electronic transistor with a conduction channel, electrolyte layer, and electrochemical gate layer that changes conductivity based on ion migration in response to applied voltage pulses, allowing predictable tuning of conductivity through controlled ion movement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If ionic liquid gate is used to control source-to-drain resistance, then memristor-like functions are achieved, but integration with solid-state devices becomes difficult and switching speed decreases

Engineering Contradiction:
Improvememristor-like functionVSAvoidintegration difficulty
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent changes the physical state of the electrolyte from liquid to solid, fundamentally altering the device characteristics. This parameter change enables integration with solid-state devices while maintaining the ability to control source-to-drain resistance through ionic migration, thus resolving the contradiction between achieving memristor-like functions and integration difficulty

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The solid electrolyte layer acts as a consumable ionic reservoir that enables solid-state operation. By using a solid electrolyte instead of liquid, the device becomes compatible with solid-state fabrication processes, resolving the integration difficulty while maintaining the essential ionic control mechanism

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Adaptability or versatility

If ionic liquid gate is used to control source-to-drain resistance, then memristor-like functions are achieved, but switching speed becomes slow

Engineering Contradiction:
Improvememristor-like functionVSAvoidswitching speed
Core Design Contradiction:
Adaptability or versatilityVSSpeed

Solution Approach 1:

Changing the electrolyte from liquid to solid state fundamentally improves switching speed. The solid electrolyte enables faster ionic migration and more rapid conductance switching while maintaining the memristor-like functionality of controlling source-to-drain resistance through ionic accumulation and depletion

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If voltage pulses are applied to migrate ions in the channel, then conductivity changes are achieved, but read noise and write noise occur

Engineering Contradiction:
Improveconductivity controlVSAvoidread/write accuracy
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The solid electrolyte layer acts as an intermediary between the gate electrode and the conduction channel. It provides controlled ionic transport that reduces noise by mediating the interaction between applied voltage and channel conductance, enabling more reliable read and write operations while maintaining ease of conductivity control

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The use of solid electrolyte changes the ionic transport parameters, providing more controlled and predictable ion migration. This parameter change reduces stochastic noise effects and improves the linearity of conductance modulation, thereby improving read/write accuracy while maintaining ease of operation

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If ion concentration in the channel is increased to improve conductivity, then conductance control is enhanced, but device linearity deteriorates due to write non-linearity

Engineering Contradiction:
Improveconductance controlVSAvoidwrite linearity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The solid electrolyte serves as an intermediary that provides linear ionic transport in response to gate voltage. This intermediary layer ensures that the relationship between applied voltage and resulting conductance change remains linear, improving write precision while maintaining ease of conductance control through the conduction channel

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

Changing from liquid to solid electrolyte modifies the ionic transport parameters, creating a more linear relationship between gate voltage and channel conductance. This parameter change eliminates the write non-linearity issue while preserving the ability to easily control conductance by adjusting ion concentration in the channel

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ionic electronic transistor achieves predictable and reversible conductivity changes, enabling efficient and linear control of conductance states, suitable for neuromorphic computing applications with fast response times.

Implementation Method 1

The conduction channel comprises a material with a conductivity that can be changed responsive to migration of ions into or out of the channel

Methodology Applied
Scientific EffectIon migration: Electrophoresis

Implementation Method 2

The electrolyte comprises a material that prevents migration of ions between the electrochemical gate layer and the conducting channel layer absent a voltage being applied

Methodology Applied
Scientific EffectElectrolyte barrier effect: Semipermeable Membrane

Implementation Method 3

The electrochemical gate layer comprises a material that can accept ions from or provide ions to the conducting channel layer

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Data Source

PatentUS10429343B1Tunable ionic electronic transistor
Publication Date: 2019.10.01 NATIONAL TECHNOLOGY & ENGINEERING SOLUTIONS OF SANDIA LLC
  • US10429343B1 patent drawing
  • US10429343B1 patent drawing
  • US10429343B1 patent drawing

AI summary

Various technologies pertaining to a transistor having a variable-conductance channel with a non-volatile tunable conductance are described herein. The transistor comprises source and drain electrodes separated by a conducting channel layer. The conducting channel layer is separated from an electrochemical gate (ECG) layer by an electrolyte layer that prevents migration of electrons between the channel and the ECG but allows ion migration. When a voltage is applied between the channel and the ECG, electrons flow from one to the other, which causes a migration of ions from the channel to the ECG or vice versa. As ions move into or out of the channel layer, the conductance of the channel changes. When the voltage is removed, the channel maintains its conductance state.