Ir Blue Phosphorescent Compound for High-Purity OLED Emission

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Solution Overview

Problem

Conventional organic electroluminescent devices have limitations in light emission efficiency and lifetime for blue light-emitting materials due to the lack of a proper host material, resulting in low efficiency and short lifetime compared to red and green phosphorescent materials.

Innovation Solution

A dark blue phosphorescent compound represented by specific Ir compounds with various ligands is developed, which can be used as a dopant or coloring substance in organic electroluminescent devices, enhancing color purity and emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional phosphorescent materials are used for blue light emission, then light emission can be achieved, but the efficiency and lifetime are low compared to red and green phosphorescent materials

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure of phosphorescent materials by introducing specific ligand combinations (ppy, pic, F2ppy) coordinated with Ir metal centers, changing the electronic and optical parameters to achieve dark blue emission with high efficiency and improved stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite phosphorescent materials combining Ir metal centers with organic ligands (picolinic acid derivatives and fluoro-substituted phenylpyridine) to develop new blue-emitting materials with superior performance compared to conventional single-component materials

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If blue light emitting materials are developed without proper host material, then material synthesis can proceed, but color purity and emission efficiency remain insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidemission efficiency
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

The patent introduces fluorine substitution at specific positions on the phenylpyridine ligand structure, creating localized electronic modifications that enhance the phosphorescent properties and achieve dark blue emission with high color purity (y < 0.203 in NTSC chromaticity diagram)

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Ir compound-based blue phosphorescent material achieves high color purity and low power consumption, leading to improved luminance, efficiency, and extended lifetime in organic electroluminescent devices.

Implementation Method 1

light emission through conversion from a triplet excited state (T1) to a ground state (SO) is phosphorescence

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS7585573B2Ir compound and organic electroluminescent device using the same
Publication Date: 2009.09.08 SAMSUNG DISPLAY CO LTD
  • US7585573B2 patent drawing
  • US7585573B2 patent drawing
  • US7585573B2 patent drawing

AI summary

An Ir compound can be a blue phosphorescent material. An organic electroluminescent device can use such a material. An organic layer, such as a light emitting layer, can be composed of the Ir compound. An organic electroluminescent device including such an organic layer may exhibit high color purity and emits dark blue light. Such an organic electroluminescent device may have low consumption power.