Iridium-Cerium Sintered Electron Source With Lower Work Function

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Solution Overview

Problem

Sintered bodies composed of iridium and cerium exhibit a large work function, limiting their practical use as electron sources.

Innovation Solution

A method involving heating a sintered body of iridium and cerium at 1400 to 1800°C for 0.5 hours or more in a low oxygen atmosphere (10 -1< Pa or less) to produce a sintered material with a work function of 3.8 eV or less, achieved through crystallization and precipitation of metal iridium on the surface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a sintered body of iridium and cerium is used as an electron source, then the material structure is simple and easy to manufacture, but the work function is large which limits electron emission performance

Engineering Contradiction:
Improveease of manufactureVSAvoidwork function
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies parameter changes by heating the sintered body at high temperature (1400-1800°C) for extended periods (0.5-100 hours) in controlled oxygen atmospheres. This thermal treatment transforms the material's work function from 4.1-4.3 eV to 3.8 eV or less, significantly improving electron emission while maintaining the sintered body structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining iridium and cerium in specific ratios (Ir:Ce = 4:1 to 9:1) to create a sintered body with optimized properties. The composite structure allows cerium to lower the work function while iridium provides structural stability, achieving both manufacturability and improved electron emission

Inventive Principle:
Principle #40Composite materials

2Reliability

If the sintered body is heated at high temperature for extended periods, then the work function decreases to enable practical electron source application, but the manufacturing process becomes more complex and time-consuming

Engineering Contradiction:
Improvework functionVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes heating parameters (temperature, time, oxygen partial pressure) to achieve the desired work function reduction with controlled process complexity. By establishing specific parameter ranges (1400-1800°C, 0.5-100 hours, controlled oxygen atmosphere), the process becomes reproducible and manageable despite the extended treatment requirements

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting sintered material achieves a sufficiently small work function, enabling high current density under low vacuum conditions, suitable for electron sources in devices like electron microscopes and semiconductor inspection devices.

Implementation Method 1

the sintered body is crystalized by heating to form a crystal body

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

metal iridium is precipitated on the surface of the crystal body

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 3

heating the sintered body at a temperature of 1400 to 1800°C for 0.5 hours or more

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

the emitter includes an electron source and a heater that heats the electron source, and the heater is energized to heat the electron source, thereby obtaining emission current

Methodology Applied
Scientific EffectThermionic emission: Thermionic Emission

Data Source

PatentEP4679479A1Sintered material, method for producing same, and electron source and device provided with same
Publication Date: 2026.01.14 DENKA CO LTD
  • EP4679479A1 patent drawingFigure 1
  • EP4679479A1 patent drawingFigure 2
  • EP4679479A1 patent drawingFigure 3

AI summary

A method for producing a sintered material, the sintered material being constituted by iridium and cerium, and the method including: a step of preparing a sintered body constituted by iridium and cerium; and a step of heating the sintered body at a temperature of 1400 to 1800°C for 0.5 hours or more in an atmosphere having an oxygen partial pressure of 10-1 Pa or less to obtain the sintered material. A sintered material constituted by iridium and cerium, having a work function of 3.8 eV or less.