Iridium Complex Ligand Tuning for Saturated OLED Emission

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Solution Overview

Problem

Current organic light emitting diodes (OLEDs) face challenges in achieving saturated red, green, and blue emissions for full color displays, which is essential for industry standards.

Innovation Solution

A compound of the form Ir(LA)m(LB)n(LC)p is disclosed, where LA, LB, and LC are specific ligands with defined structures, and m, n, and p are variables that satisfy the condition m+n+p=3, enabling the formation of a 5-membered chelate ring and optimizing emission properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic materials are used in OLEDs, then the devices can be fabricated on flexible substrates with cost advantages, but the emission characteristics cannot achieve saturated red, green, and blue colors required for full color displays

Engineering Contradiction:
Improveemission saturationVSAvoidcolor range
Core Design Contradiction:
Illumination intensityVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by modifying the chemical structure of organic compounds, specifically developing iridium complex compounds with specific ligand configurations (Formula IA, IB, and II) to achieve saturated red, green, and blue emissions. The patent changes molecular parameters including ligand types (LA, LB, LC), coordination geometry, and electronic structure to tune emission wavelengths and achieve industry-standard color saturation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating iridium complex compounds composed of multiple ligand components (LA, LB, LC) with specific structures. These composite molecular structures combine different ligand functionalities to achieve the desired emission properties, where LA and LB are specific organic ligands and LC is a bidentate ligand, forming a composite complex with enhanced color saturation.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If white OLED with absorption filters is used to produce colors, then the device structure becomes simpler, but the emission saturation and color quality decrease compared to direct emissive approaches

Engineering Contradiction:
Improvecolor saturationVSAvoidemissive layer structure
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent changes the emission parameters of the organic compounds themselves to directly produce saturated colors, eliminating the need for absorption filters. By modifying the HOMO-LUMO energy gaps and molecular orbitals of the iridium complexes, the patent achieves direct emission of saturated red, green, and blue light, improving color quality without requiring complex filter assemblies.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts and eliminates the need for absorption filter layers by developing compounds that emit saturated colors directly. Instead of using a white OLED with filters to produce colors, the patent removes the filter requirement by designing iridium complexes with intrinsic saturated color emission capabilities, simplifying the overall device structure while maintaining or improving color quality.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this compound in OLEDs enhances the emission characteristics, allowing for the production of saturated colors, thereby meeting industry standards for full color displays.

Implementation Method 1

One application for phosphorescent emissive molecules is a full color display

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 2

LA is coordinated to Ir via the dashed lines to form a 5-membered chelate ring

Methodology Applied
Scientific EffectChelation:

Data Source

PatentUS20250072278A1Organic electroluminescent materials and devices
Publication Date: 2025.02.27 UNIVERSAL DISPLAY CORP
  • US20250072278A1 patent drawing
  • US20250072278A1 patent drawing
  • US20250072278A1 patent drawing

AI summary

A heteroleptic compound of formula Ir(LA)m(LB)n(LC)p is provided wherein LA has a structure of Formula IA,or Formula IB,LB has a structure of Formula II,and LC is a bidentate ligand; and wherein m is 1 or 2; n is 1 or 2; and p is 0 or 1; and m+n+p=3 In Formulae I and II, moieties A and D are heterocyclic ring or a polycyclic ring system; each of X1 to X12 is C or N; Ring B is connected to moiety A by a C; at least one of X9 to X12 is N; Y is a linking group that forms a 5-membered ring; each R, R′, R″, RA, RB, RC, RD, and RE is hydrogen or a General Substituent as defined herein; LA forms a 5-membered chelate ring with Ir. Formulations, OLEDs, and consumer products containing the compound are also provided.