Iridium Nanopowder Sintering for Seamless High-Purity Parts

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Solution Overview

Problem

The traditional production of iridium products is hindered by high sensitivity to doping elements, leading to brittle fracture, and involves energy-intensive multi-step refining processes with significant equipment costs and material losses, resulting in high prices and limited output.

Innovation Solution

The use of high-purity metallic iridium nanopowder, produced through a combination of hydrometallurgical, electrochemical, and pyrometallurgical processes, is converted into nanopowder with specific properties and then processed via isostatic pressing at room temperature followed by baking, eliminating the need for electron beam vacuum remelting and reducing production cycles and losses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional multi-stage vacuum electron beam remelting is used to produce monocrystalline iridium, then chemical purity is improved (no more than 0.003% foreign content), but production cost and energy consumption increase significantly

Engineering Contradiction:
Improvechemical purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by stationary object

Solution Approach 1:

The invention changes the physical state parameter of iridium from monocrystalline form to nanopowder form (particle size 1-100 nm). This parameter change enables the use of simpler sintering processes instead of energy-intensive vacuum electron beam remelting, while maintaining high chemical purity (99.99% or higher) through alternative purification methods during nanopowder production

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the mechanical/thermal vacuum electron beam remelting system with a chemical-hydrometallurgical system for producing nanopowder. The nanopowder production uses chemical reduction and precipitation methods in liquid phase, which consume significantly less energy than vacuum electron beam processes, while achieving equal or superior purity levels

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If traditional vacuum electron beam remelting process is used, then product reliability is improved through high purity monocrystalline material, but production cycle time increases

Engineering Contradiction:
Improveproduct reliabilityVSAvoidproduction cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention performs preliminary purification and nanopowder production in advance through hydrometallurgical and chemical processes. The nanopowder is pre-sintered to form green compact bodies before final product fabrication, eliminating the need for time-consuming vacuum electron beam remelting steps during actual production

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention segments the production process into independent stages: nanopowder production, green compact formation, and final sintering. This segmentation allows parallel processing and eliminates sequential dependencies of traditional methods, significantly reducing total production cycle time while maintaining product reliability through controlled purification at each stage

Inventive Principle:
Principle #1Segmentation

3Strength

If traditional iridium manufacturing technology is used, then material strength is maintained through monocrystalline structure, but material losses increase during processing

Engineering Contradiction:
Improvematerial strengthVSAvoidmaterial losses
Core Design Contradiction:
StrengthVSLoss of substance

Solution Approach 1:

The invention changes the microstructural parameter from monocrystalline to nanocrystalline/nanopowder structure. This parameter change enables near-net-shape sintering processes with material utilization exceeding 95%, compared to 70-80% in traditional methods. The nanopowder's high surface area to volume ratio facilitates complete densification during sintering, minimizing material losses

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality control through controlled nanopowder sintering, where specific regions are densified to different degrees based on product requirements. This allows optimization of material distribution and reduces waste by precisely controlling where material is placed and how much is used in each product region

Inventive Principle:
Principle #3Local quality

4Ease of manufacture

If conventional iridium powder is used for product formation, then production simplicity is maintained, but product performance deteriorates due to interstitial defects and brittleness

Engineering Contradiction:
Improveproduction simplicityVSAvoidproduct performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the particle size parameter to nanoscale (1-100 nm), which fundamentally alters the sintering behavior and final product structure. The nanopowder forms dense, defect-free structures during sintering due to enhanced diffusion and atomic mobility at the nanoscale, eliminating interstitial defects and improving mechanical properties while maintaining production simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure at the nanoscale where ultra-fine iridium particles are distributed uniformly in the matrix. This nanocomposite structure provides superior mechanical properties including increased strength, ductility, and resistance to brittle fracture compared to conventional coarse-grained iridium, while the simple sintering process maintains ease of manufacture

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases metal yield by 1.5 times, reduces production costs by 1.5-2 times, and enhances consumer properties by minimizing interstitial defects, leading to improved utility and operational performance in severe conditions.

Implementation Method 1

High-purity metallic iridium nanopowder is obtained as a result of the original combination of hydrometallurgical, electrochemical and pyrometallurgical processes

Methodology Applied
Scientific EffectHydrometallurgical process:

Implementation Method 2

High-purity metallic iridium nanopowder is obtained as a result of the original combination of hydrometallurgical, electrochemical and pyrometallurgical processes

Methodology Applied
Scientific EffectElectrochemical process:

Implementation Method 3

High-purity metallic iridium nanopowder is obtained as a result of the original combination of hydrometallurgical, electrochemical and pyrometallurgical processes

Methodology Applied
Scientific EffectPyrometallurgical process:

Implementation Method 4

from which the final product is obtained by pressing at room temperature using subsequent baking processes

Methodology Applied
Scientific EffectIsostatic pressing: Hot Isostatic Pressing

Implementation Method 5

from which the final product is obtained by pressing at room temperature using subsequent baking processes

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentEP3388170B1Method for producing articles from iridium metal
Publication Date: 2021.08.11 OBSCHESTVO S OGRANICHENNOI OTVETSTVENNOSTYU NAUCHNO PROIZVODSTVENNOE OBEDINENIE METALLY URALA

AI summary

The invention relates to a method for producing products from metallic iridium, based on the use of chemically high-purity metal (not less than 99.99%) obtained by electron beam remelting. The required material is converted into a nanopowder with a dispersion of less than 100 nm, from which seamless products of various configurations are obtained by pressing the nanopowder at room temperature followed by a baking process. An isotropic structure with a core size of 100–300 nm is achieved, exhibiting improved strength properties of 200–300%.