Iridium Guest Material for OLED Light Stability and Evaporation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current guest materials in OLEDs have poor luminous efficiency and light stability, and high evaporation temperatures, limiting the performance and development of organic electroluminescent display devices.

Innovation Solution

A compound with a specific structure that coordinates with iridium (Ir) is used as a guest material in the light-emitting layer, allowing for regulation of light-emitting wavelength, improving luminous efficiency, and reducing evaporation temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If current guest materials are used in OLEDs, then the device can operate, but the luminous efficiency and light stability are poor

Engineering Contradiction:
Improvelight stabilityVSAvoidluminous efficiency
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent modifies the molecular structure parameters of guest materials by incorporating specific heterocyclic rings (triazole, tetrazole, oxazole, thiazole) and adjusting ligand configurations to optimize the balance between luminous efficiency and light stability. This structural parameter change enables the material to achieve both high reliability and energy efficiency simultaneously.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite guest materials by combining iridium centers with specially designed organic ligands containing heterocyclic rings. This composite structure integrates the advantages of both metal centers (for high luminous efficiency) and heterocyclic ligands (for enhanced light stability), resolving the contradiction between the two performance parameters.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If current guest materials are used in OLEDs, then the device can function, but the evaporation temperature is high

Engineering Contradiction:
Improveprocessing difficultyVSAvoidevaporation temperature
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the molecular weight and structural complexity parameters of the guest materials by using coordinated iridium complexes with specific ligand arrangements. These parameter changes result in lower evaporation temperatures, making the materials easier to process and manufacture while maintaining device functionality.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If the compound structure is optimized for light emission, then luminous efficiency improves, but the molecular weight increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidmolecular weight
Core Design Contradiction:
Loss of energyVSWeight of moving object

Solution Approach 1:

The patent segments the guest material structure into functional modules: the iridium center for light emission, heterocyclic rings for stability, and ligands for coordination. This segmentation allows optimization of luminous efficiency through the iridium core while keeping the overall molecular weight manageable through efficient ligand design.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The designed ligands serve multiple functions simultaneously: they coordinate with the iridium center to enable light emission, provide structural stability for light stability, and maintain appropriate molecular weight through their compact heterocyclic structures. This multi-functionality resolves the contradiction between luminous efficiency and molecular weight.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances luminous efficiency, light stability, and service life of OLEDs while lowering the evaporation temperature, facilitating better processing and display performance.

Implementation Method 1

the luminescent layer contains a host material and a doped guest material, and the guest material is mainly used to improve the intersystem crossing efficiency between singlet state and triplet state of molecules

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240124770A1Compound, guest material of light-emitting layer, organic electroluminescent device, and display device
Publication Date: 2024.04.18 BEIJING NORMAL UNIVERSITY
  • US20240124770A1 patent drawing
  • US20240124770A1 patent drawing
  • US20240124770A1 patent drawing

AI summary

The present application provides a compound of general formula (I), capable of being used for an organic electroluminescent device as a guest material of a light-emitting layer. The compound contains a structure in which a natural heterocyclic ring coordinates with iridium (Ir), and a light-emitting wavelength of the compound can be effectively regulated. Using the compound as the guest material of the light-emitting layer facilitates the improvement of luminous efficiency and light stability of the organic electroluminescent device. In addition, the compound provided by the present application has a small molecular weight, is applied to a light-emitting layer, has a low evaporation temperature, and facilitates processing. The present application also provides a guest material of a light-emitting layer containing the compound of general formula (I), an organic electroluminescent device, and a display device.