Iridium OLED Emitter Compounds for Saturated RGB Emission

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face challenges in achieving saturated colors for full-color displays, particularly in producing red, green, and blue emissions efficiently, which is crucial for advanced display technologies.

Innovation Solution

A novel compound comprising a ligand complexed to Ir, featuring multiple fused heterocyclic or carbocyclic ring structures, allows for tridentate, tetradentate, pentadentate, or hexadentate coordination, enhancing the photoluminescent properties and emission efficiency in OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional organic materials are used in OLEDs, then the devices can be fabricated with cost advantages and flexibility, but the emission efficiency and color saturation are insufficient for full-color displays

Engineering Contradiction:
Improvefabrication cost and flexibilityVSAvoidemission efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of organic emitters by incorporating specific heterocyclic ring systems (pyrrole, imidazole, triazole) and adjusting substituents to optimize photoluminescent properties. This changes the electronic and optical parameters of the material to achieve both high emission efficiency and color saturation while maintaining processability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite molecular structures combining multiple heterocyclic rings and substituent groups to create emitters with tailored properties. These composite organic materials achieve superior emission characteristics compared to conventional single-structure organic compounds

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional organic materials are used in OLEDs, then the devices can be fabricated with cost advantages and flexibility, but the color saturation for red, green, and blue emissions is insufficient

Engineering Contradiction:
Improvefabrication cost and flexibilityVSAvoidcolor saturation
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent adjusts molecular parameters including ring substitution patterns, heteroatom types, and substituent groups to precisely control emission wavelengths and color coordinates. This enables achievement of saturated red, green, and blue emissions required for display applications

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces specific functional groups and heterocyclic units at particular positions within the molecular structure to locally enhance light-emitting properties. Different regions of the molecule are optimized for specific emission characteristics to achieve overall color saturation

Inventive Principle:
Principle #3Local quality

3Productivity

If advanced heterocyclic ligand structures are used to improve emission efficiency, then the photoluminescent properties are enhanced, but the molecular complexity increases

Engineering Contradiction:
Improveemission efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent divides the complex ligand structure into modular heterocyclic units (pyrrole, imidazole, triazole rings) that can be systematically combined. This segmentation allows for rational design of complex molecules with controlled photoluminescent properties while maintaining synthetic feasibility

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves the emission efficiency and color saturation in OLEDs, enabling the production of high-quality, full-color displays with enhanced performance and flexibility.

Implementation Method 1

A novel compound comprising a ligand complexed to Ir, featuring multiple fused heterocyclic or carbocyclic ring structures, allows for tridentate, tetradentate, pentadentate, or hexadentate coordination, enhancing the photoluminescent properties and emission efficiency in OLEDs

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS12035613B2Organic electroluminescent materials and devices
Publication Date: 2024.07.09 UNIVERSAL DISPLAY CORP
  • US12035613B2 patent drawing
  • US12035613B2 patent drawing
  • US12035613B2 patent drawing

AI summary

Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.