Iridium OLED Compounds for Saturated Color Emission

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated colors, particularly in producing red, green, and blue emissions efficiently, which is crucial for full-color displays, as existing materials and methods struggle to meet industry standards for color accuracy and efficiency.

Innovation Solution

A novel compound of Formula I is introduced, which includes specific monocyclic or polycyclic ring systems and electron-withdrawing groups, used in OLED formulations and devices to enhance color emission properties, allowing for improved color accuracy and efficiency by optimizing the energy levels and structural configurations of the organic layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional organic materials are used in OLEDs, then device flexibility and cost advantages are achieved, but color saturation and emission efficiency fail to meet industry standards

Engineering Contradiction:
Improvecolor accuracyVSAvoidemission efficiency
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by changing parameters such as ring system configuration (monocyclic to polycyclic), heteroatom composition (Z1-Z6 being C or N), and substituent groups (RA-RF) to optimize HOMO-LUMO energy gaps. These parameter changes enable tailored emission wavelengths that achieve both saturated colors and high emission efficiency simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite molecular structures combining multiple ring systems (moieties A-F) with specific heteroatoms and substituent groups to create molecules with dual functionality: achieving saturated color emission through controlled energy levels while maintaining high quantum efficiency. The composite structure allows simultaneous optimization of optical properties and electrical characteristics

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If white OLED with absorption filters is used to produce saturated colors, then color accuracy improves, but device complexity and light loss increase

Engineering Contradiction:
Improvecolor saturationVSAvoidlight loss
Core Design Contradiction:
Measurement precisionVSLoss of energy

Solution Approach 1:

The patent extracts the color filtering function from separate absorption filters and integrates it directly into the emissive layer through molecular design. The organic compounds are engineered to emit specific saturated colors directly (red, green, or blue) without requiring external filters, thereby eliminating the energy loss associated with absorbing unwanted wavelengths

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention introduces specially designed organic compounds as intermediaries that convert electrical energy directly into saturated color emission. These compounds act as mediators between the electrical input and the desired optical output, achieving color saturation through controlled molecular emission rather than through filtering white light

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enables OLEDs to produce saturated colors with improved color purity and efficiency, meeting industry standards for full-color displays by optimizing the energy levels and structural configurations of the organic layers, leading to better performance in display applications.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240365658A1Organic electroluminescent materials and devices
Publication Date: 2024.10.31 UNIVERSAL DISPLAY CORP
  • US20240365658A1 patent drawing
  • US20240365658A1 patent drawing
  • US20240365658A1 patent drawing

AI summary

Provided are organometallic compounds comprising an Ir atom as the central metal atom which is coordinated by two three-dentate ligands. Also provided are formulations comprising these organometallic compounds comprising an Ir atom. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds comprising an Ir atom.