Iridium Oxide Catalyst for Oxygen Evolution Reaction Durability

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Solution Overview

Problem

Conventional oxygen evolution reaction catalysts in proton exchange membrane fuel cells are prone to degradation due to high electrochemical potentials during operational irregularities such as cell reversal and start-up/shut-down, leading to irreversible damage and loss of active surface area.

Innovation Solution

A catalyst comprising particles of iridium oxide and a metal oxide, prepared by flame spray pyrolysis with a high surface area and controlled particle size, is used to facilitate the oxygen evolution reaction, providing enhanced performance and resistance to degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional oxygen evolution reaction catalysts are used in PEMFC, then the fuel cell can operate normally, but the catalyst suffers irreversible damage and loses active surface area during high potential excursions

Engineering Contradiction:
Improvecatalyst durabilityVSAvoidcarbon corrosion and metal sintering
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies the principle of converting harm into benefit by using flame spray pyrolysis to create a catalyst structure that transforms the harmful effects of high potential excursions. The unique particle morphology and composition resulting from the flame spray process provide inherent resistance to carbon corrosion and metal sintering, turning the previously damaging conditions into opportunities for demonstrating catalyst robustness.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent employs parameter changes by modifying the physical and chemical properties of the catalyst through flame spray pyrolysis. Key parameters including particle size distribution, surface area, and compositional homogeneity are controlled during the spray process to optimize catalyst performance. The flame temperature, spray rate, and precursor composition are adjusted to achieve the desired catalyst characteristics that resist degradation.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If flame spray pyrolysis is used to prepare the catalyst, then the catalyst achieves high surface area and controlled particle size, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveparticle size controlVSAvoidflame spray pyrolysis process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces traditional mechanical mixing and drying methods with flame spray pyrolysis, a thermal field-based process. This substitution allows for direct formation of catalyst particles with controlled morphology and composition in a single step, eliminating the need for multiple processing stages and reducing overall manufacturing complexity despite the advanced equipment required.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes phase transitions inherent in the flame spray pyrolysis process to achieve precise particle size control. The rapid heating and cooling cycles during spraying cause controlled phase changes in the precursor materials, leading to uniform particle formation. This phase transition mechanism provides inherent control over particle morphology without requiring complex post-processing steps.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst exhibits improved oxygen evolution reaction efficiency and durability, with increased resistance to carbon corrosion and sintering, allowing for prolonged operation without significant degradation.

Implementation Method 1

A catalyst comprising particles of iridium oxide and a metal oxide, wherein the catalyst is prepared by subjecting a precursor mixture to flame spray pyrolysis

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

flame spray pyrolysis

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

a catalyst for the oxygen evolution reaction (water electrolysis)

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

oxygen evolution reaction (water electrolysis)

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Data Source

PatentUS10615423B2Catalyst
Publication Date: 2020.04.07 JOHNSON MATTHEY HYDROGEN TECH LTD
  • US10615423B2 patent drawing
  • US10615423B2 patent drawing

AI summary

A catalyst comprising particles of iridium oxide and a metal oxide (M oxide), wherein the metal oxide is selected from the group consisting of a Group 4 metal oxide, a Group 5 metal oxide, a Group 7 metal oxide and antimony oxide, wherein the catalyst is prepared by subjecting a precursor mixture to flame spray pyrolysis, wherein the precursor mixture comprises a solvent, an iridium oxide precursor and a metal oxide precursor is disclosed. The catalyst has particular use in catalysing the oxygen evolution reaction.