Iridium-Palladium Catalyst Electrode for Lower OER Overpotential

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Solution Overview

Problem

The water electrolysis process faces inefficiencies due to a higher overpotential required for the oxygen evolution reaction (OER) compared to the hydrogen evolution reaction (HER), necessitating the development of high-efficiency catalysts to lower OER overpotential.

Innovation Solution

A catalyst electrode is developed with a metal layer and a catalyst layer containing iridium and palladium, where the iridium and palladium are chemically bonded and deposited using an electrochemical method, potentially without a binder, to enhance OER performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional noble metal catalysts are used for OER, then catalytic activity is maintained, but metal loading amount is high and cost is increased

Engineering Contradiction:
Improvemetal loading amountVSAvoidcatalytic activity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses a composite catalyst layer containing both iridium and palladium metals. The synergistic effect between these two metals provides high catalytic activity for OER while reducing the overall noble metal loading amount compared to conventional single-metal catalysts. The composite structure allows each metal to contribute its unique catalytic properties, achieving enhanced performance with reduced material quantity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the ratio of iridium to palladium in the catalyst layer to achieve maximum catalytic efficiency at minimum metal loading. By adjusting the compositional parameters and deposition conditions, the catalyst achieves high OER activity with reduced noble metal content, resolving the contradiction between quantity reduction and activity maintenance.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If electrochemical deposition method is used, then catalyst layer is formed with reduced material usage, but deposition control precision is required

Engineering Contradiction:
Improvecatalyst material usageVSAvoiddeposition control
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent replaces conventional mechanical or chemical deposition methods with electrochemical deposition. This method uses electrical current to control the deposition of iridium and palladium onto the substrate, enabling precise control of material distribution and thickness while minimizing overall material usage. The electrochemical process allows for controlled reduction of metal ions to metal atoms at the electrode surface.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The electrochemical deposition process employs feedback control through monitoring of current, voltage, and deposition rate. By adjusting deposition parameters in real-time based on measured values, the method achieves precise control over catalyst layer formation, ensuring uniform distribution and optimal thickness while reducing total material consumption.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst electrode achieves improved OER performance with a reduced metal loading amount compared to conventional noble metal catalysts, demonstrating potential for enhanced efficiency in water electrolysis systems.

Implementation Method 1

the iridium and palladium may be electrochemically deposited on the metal layer

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Implementation Method 2

at least a part of the iridium and palladium included in the catalyst layer may be chemically bonded with each other

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP4546471A1Catalyst electrode, method for manufacturing catalyst electrode, and membrane electrode assembly
Publication Date: 2025.04.30 SK INNOVATION CO LTD
  • EP4546471A1 patent drawingFigure 1
  • EP4546471A1 patent drawingFigure 2
  • EP4546471A1 patent drawingFigure 3

AI summary

A catalyst electrode according to an embodiment of the present disclosure includes a metal layer; and a catalyst layer formed on the metal layer, wherein the catalyst layer includes iridium and palladium.