Iron Nitride Magnet Casting With Applied Field Alignment

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Solution Overview

Problem

Current permanent magnets rely heavily on rare earth elements, which are scarce and expensive, and their production contributes to environmental deterioration and high manufacturing costs, due to processes like crushing, compressing, and sintering at high temperatures.

Innovation Solution

The development of techniques for forming iron nitride magnetic materials with uniaxial magnetic anisotropy, such as α″-Fe16N2, through casting and consolidation in an applied magnetic field, which aligns crystal orientations and increases magnetic anisotropy, reducing the need for rare earth elements and lowering production costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If rare earth elements are used to produce permanent magnets, then high energy product is achieved, but manufacturing cost increases and environmental deterioration occurs

Engineering Contradiction:
Improveenergy productVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive rare earth elements with abundant, inexpensive iron-based materials. The iron nitride magnets use common materials (iron, nitrogen) instead of scarce rare earth elements like neodymium, achieving comparable magnetic performance while dramatically reducing material cost and eliminating the need for expensive crushing, compressing, and sintering processes.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If rare earth elements are used in permanent magnets, then high energy product is achieved, but supply shortages and price increases occur

Engineering Contradiction:
Improveenergy productVSAvoidsupply availability
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention substitutes scarce rare earth elements with abundant iron and nitrogen. Iron is one of the most abundant elements in the Earth's crust, and nitrogen is readily available from the atmosphere. This substitution ensures long-term supply security and price stability while maintaining high magnetic energy product through the formation of iron nitride phases with uniaxial magnetic anisotropy.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Ease of manufacture

If conventional sintering process is used for magnet fabrication, then permanent magnets are formed, but high manufacturing cost and environmental impact result

Engineering Contradiction:
Improvemagnet formationVSAvoidenvironmental impact
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent fundamentally changes the manufacturing parameters by eliminating the high-temperature sintering process (typically over 1000°C) required for conventional rare earth magnets. Instead, the invention uses lower-temperature processing methods to form iron nitride magnets, significantly reducing energy consumption and environmental impact while maintaining magnetic performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the mechanical crushing and compressing steps with a chemical synthesis approach. Rather than mechanically processing rare earth materials, the patent uses chemical reactions between iron and nitrogen to directly form the magnetic iron nitride phase, eliminating dust generation and mechanical wear while reducing overall manufacturing complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These techniques produce bulk permanent magnets with high saturation magnetization and magnetic anisotropy constants, achieving an energy product comparable to rare earth magnets while reducing environmental impact and production costs.

Implementation Method 1

By applying a magnetic field during the casting process, the nucleation and grown of iron nitride crystals may be influenced such that growth of crystals having a predetermined orientation may be energetically favorable

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

iron nitride crystals having (002) or (004) crystal planes substantially parallel to the direction of the applied magnetic field may be more energetically favorable

Methodology Applied
Scientific EffectMagnetic anisotropy: Anisotropy

Implementation Method 3

a magnetic field may be applied to the material being consolidated to substantially align magnetic easy axes of multiple workpieces including at least one iron-based phase domain including uniaxial magnetic anisotropy

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 4

magnetic easy axes of multiple workpieces including at least one iron-based phase domain including uniaxial magnetic anisotropy may be aligned substantially parallel to the direction of the applied magnetic field

Methodology Applied
Scientific EffectMagnetic anisotropy: Anisotropy

Data Source

PatentUS20240290539A1Applied magnetic field synthesis and processing of iron nitride magnetic materials
Publication Date: 2024.08.29 REGENTS OF THE UNIVERSITY OF MINNESOTA
  • US20240290539A1 patent drawing
  • US20240290539A1 patent drawing
  • US20240290539A1 patent drawing

AI summary

Techniques are disclosed concerning applied magnetic field synthesis and processing of iron nitride magnetic materials. Some methods concern casting a material including iron in the presence of an applied magnetic field to form a workpiece including at least one iron-based phase domain including uniaxial magnetic anisotropy, wherein the applied magnetic field has a strength of at least about 0.01 Tesla (T). Also disclosed are workpieces made by such methods, apparatus for making such workpieces and bulk materials made by such methods.