Iron Ore Catalyst Preparation via Direct Impregnation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional methods for preparing iron-based catalysts are costly, environmentally unfriendly, and result in catalysts with low productivity and poor CO conversion ratios, often requiring extensive washing processes and high nitrate usage.

Innovation Solution

A method involving the direct use of iron ore, grinding to specific particle sizes, and impregnation with metals like copper or manganese, along with alkali metals, to create a catalyst with enhanced reactivity and reduced nitrate usage, eliminating the need for washing and minimizing water consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional precipitation method is used to prepare iron-based catalyst, then reaction activity of Fischer-Tropsch synthesis is improved, but process complexity increases and environmental pollution occurs due to extensive washing with distilled water

Engineering Contradiction:
Improvereaction activityVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the harmful washing step from the conventional precipitation process. By using iron ore directly as raw material instead of iron nitrate, the method removes the need for extensive distilled water washing, thereby simplifying the process while maintaining catalyst performance and reducing environmental pollution.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces expensive and environmentally burdensome chemicals (iron nitrate, extensive washing water) with cheap and sustainable alternatives (iron ore, minimal water). This substitution maintains catalyst effectiveness while dramatically reducing process complexity and environmental impact.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If iron nitrate is used as raw material for catalyst preparation, then catalyst performance can be achieved, but environmental pollution increases due to large amounts of nitrate discharge

Engineering Contradiction:
Improvecatalyst performanceVSAvoidnitrate pollution
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention replaces expensive and polluting iron nitrate with cheap and environmentally friendly iron ore. This substitution eliminates large amounts of nitrate discharge while maintaining catalyst performance, thereby resolving the contradiction between achieving catalyst performance and reducing environmental pollution.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention converts the traditionally harmful precipitation process into a beneficial direct impregnation process. By using iron ore directly, the method eliminates nitrate pollution while maintaining catalyst effectiveness, turning a harmful process into an environmentally friendly one.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If extensive washing process is applied to remove residue, then catalyst purity is improved, but water consumption increases causing environmental pollution

Engineering Contradiction:
Improvecatalyst purityVSAvoidwater consumption
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The invention extracts and eliminates the extensive washing step from the conventional process. By using iron ore directly as raw material, the method achieves catalyst purity without requiring large amounts of distilled water, thereby resolving the contradiction between catalyst purity and water consumption.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention makes the process self-sufficient by eliminating the need for extensive external washing. The direct impregnation method using iron ore inherently produces a clean catalyst without requiring additional water-intensive purification steps, thereby reducing water consumption while maintaining purity.

Inventive Principle:
Principle #25Self-service

4Ease of manufacture

If conventional catalyst preparation methods are used, then catalyst can be produced, but production cost increases due to multiple processing steps and chemical usage

Engineering Contradiction:
Improvecatalyst productionVSAvoidprocessing cost
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The invention extracts and removes unnecessary processing steps and chemicals from the conventional method. By using iron ore directly and eliminating extensive washing and multiple treatment steps, the method simplifies the manufacturing process while reducing chemical usage and production costs.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces expensive raw materials (iron nitrate) and processing chemicals with cheap alternatives (iron ore). This substitution dramatically reduces material costs while maintaining catalyst effectiveness, thereby resolving the contradiction between ease of manufacture and production cost.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces an iron-based catalyst with improved CO conversion ratios and C5+ selectivity, reducing processing costs and environmental impact while maintaining high catalyst performance.

Implementation Method 1

impregnating the iron ore particles with a first metal and second metal

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9789472B2Method for preparing iron-based catalyst and iron-based catalyst prepared by the same
Publication Date: 2017.10.17 KOREA INST OF ENERGY RES
  • US9789472B2 patent drawing
  • US9789472B2 patent drawing
  • US9789472B2 patent drawing

AI summary

A method for preparing an iron-based catalyst, the method including preparing iron ore particles by grinding iron ore; and impregnating the iron ore particles with a first metal and second metal, wherein the first metal is selected from copper, cobalt, or manganese, or a combination thereof, and the second metal is selected from an alkali metal or alkali earth metal, or a combination thereof.